Synthesis and Gas Sorption Properties of a Metal-Azolium Framework (MAF) Material

被引：86

作者：

Lee, Jeong Yong ^{[1
]}

Roberts, John M. ^{[1
]}

Farha, Omar K. ^{[1
]}

Sarjeant, Amy A. ^{[1
]}

Scheidt, Karl A. ^{[1
]}

Hupp, Joseph T. ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 21期

关键词：

N-HETEROCYCLIC CARBENES; ORGANIC FRAMEWORKS; CARBON-DIOXIDE; PORE-SIZE; ADSORPTION; SEPARATION; STORAGE; CO2; FUNCTIONALITY; SIMULATION;

D O I：

10.1021/ic901174p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new strut containing an imidazolium tetracarboxylic acid core has been successfully incorporated into a microporous material using paddlewheel-coordinated copper(II) ions as nodes. Sorption studies conducted on this permanently microporous material imply that it can separate carbon dioxide from methane with high selectivity.

引用

页码：9971 / 9973

页数：3

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