Recent Attempts in the Design of Efficient PVC Plasticizers with Reduced Migration

被引:92
作者
Czogala, Joanna [1 ,2 ,3 ]
Pankalla, Ewa [2 ]
Turczyn, Roman [1 ]
机构
[1] Silesian Tech Univ, Dept Phys Chem & Technol Polymers, Strzody 9, PL-44100 Gliwice, Poland
[2] Grp Azoty Zaklady Azotowe Kedzierzyn SA, Res & Innovat Dept, Mostowa 30A, PL-47220 Kedzierzyn Kozle, Poland
[3] Silesian Tech Univ, Joint Doctoral Sch, Akademicka 2A, PL-44100 Gliwice, Poland
关键词
PVC; primary plasticizer; migration resistance; bio-based plasticizers; plasticizing efficiency;
D O I
10.3390/ma14040844
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper reviews the current trends in replacing commonly used plasticizers in poly(vinyl chloride), PVC, formulations by new compounds with reduced migration, leading to the enhancement in mechanical properties and better plasticizing efficiency. Novel plasticizers have been divided into three groups depending on the replacement strategy, i.e., total replacement, partial replacement, and internal plasticizers. Chemical and physical properties of PVC formulations containing a wide range of plasticizers have been compared, allowing observance of the improvements in polymer performance in comparison to PVC plasticized with conventionally applied bis(2-ethylhexyl) phthalate, di-n-octyl phthalate, bis(2-ethylhexyl) terephthalate and di-n-octyl terephthalate. Among a variety of newly developed plasticizers, we have indicated those presenting excellent migration resistance and advantageous mechanical properties, as well as those derived from natural sources. A separate chapter has been dedicated to the description of a synergistic effect of a mixture of two plasticizers, primary and secondary, that benefits in migration suppression when secondary plasticizer is added to PVC blend.
引用
收藏
页码:1 / 28
页数:28
相关论文
共 107 条
[41]   Designing anti-migration furan-based plasticizers and their plasticization properties in poly (vinyl chloride) blends [J].
He, Zhuang ;
Lu, Yanyu ;
Lin, Changqu ;
Jia, Honghua ;
Wu, Hongli ;
Cao, Fei ;
Ouyang, Pingkai .
POLYMER TESTING, 2020, 91
[42]   Nonmigratory internal plasticization of poly(vinyl chloride) via pendant triazoles bearing alkyl or polyether esters [J].
Higa, Chad M. ;
Tek, Andy T. ;
Wojtecki, Rudy J. ;
Braslau, Rebecca .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2018, 56 (21) :2397-2411
[43]   Epoxidized vegetable oil and bio-based materials as PVC plasticizer [J].
Hosney, Hadeel ;
Nadiem, Bassant ;
Ashour, Ibrahim ;
Mustafa, Ibrahim ;
El-Shibiny, Ayman .
JOURNAL OF APPLIED POLYMER SCIENCE, 2018, 135 (20)
[44]   Novel branched poly(-caprolactone) as a nonmigrating plasticizer in flexible PVC: Synthesis and characterization [J].
Huang, Yangze ;
Yu, Erlei ;
Li, Yanke ;
Wei, Zhong .
JOURNAL OF APPLIED POLYMER SCIENCE, 2018, 135 (32)
[45]  
Jakupca M., 2016, U.S. Patent, Patent No. [0,369,086, 0369086]
[46]   Application of a bio-based polyester plasticizer modified by hydrosilicon-hydrogenation reaction in soft PVC films [J].
Ji, Shufang ;
Gao, Chuanhui ;
Wang, Huizi ;
Liu, Yuetao ;
Zhang, Di ;
Zhang, Shanfa ;
Lu, Xiaotong ;
Wu, Yumin ;
Hu, Zunfu .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2019, 30 (04) :1126-1134
[47]   Graft modification of polyvinyl chloride with epoxidized biomass-based monomers for preparing flexible polyvinyl chloride materials without plasticizer migration [J].
Jia, P. ;
Ma, Y. ;
Kong, Q. ;
Xu, L. ;
Hu, Y. ;
Hu, L. ;
Zhou, Y. .
MATERIALS TODAY CHEMISTRY, 2019, 13 :49-58
[48]   Synthesis of castor oil based plasticizers containing flame retarded group and their application in poly (vinyl chloride) as secondary plasticizer [J].
Jia, Pu-You ;
Bo, Cai-Ying ;
Zhang, Li-Qiang ;
Hu, Li-Hong ;
Zhang, Meng ;
Zhou, Yong-Hong .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2015, 28 :217-224
[49]   Plasticizers Derived from Biomass Resources: A Short Review [J].
Jia, Puyou ;
Xia, Haoyu ;
Tang, Kehan ;
Zhou, Yonghong .
POLYMERS, 2018, 10 (12)
[50]   A Strategy for Nonmigrating Plasticized PVC Modified with Mannich base of Waste Cooking Oil Methyl Ester [J].
Jia, Puyou ;
Zhang, Meng ;
Hu, Lihong ;
Song, Fei ;
Feng, Guodong ;
Zhou, Yonghong .
SCIENTIFIC REPORTS, 2018, 8