Catalytic Water Oxidation by Single-Site Ruthenium Catalysts

被引：273
|
作者：
Concepcion, Javier J. [1 ]
Jurss, Jonah W. [1 ]
Norris, Michael R. [1 ]
Chen, Zuofeng [1 ]
Templeton, Joseph L. [1 ]
Meyer, Thomas J. [1 ]
机构：
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
来源：
INORGANIC CHEMISTRY | 2010年 / 49卷 / 04期
关键词：
COUPLED ELECTRON-TRANSFER; POLYPYRIDYL COMPLEXES; AQUEOUS-MEDIA; OSMIUM; REDOX;
D O I：
10.1021/ic901437e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of monomeric ruthenium polypyridyl complexes have been synthesized and characterized, and their performance as water oxidation catalysts has been evaluated. The diversity of ligand environments and how they influence rates and reaction thermodynamics create a platform for catalyst design with controllable reactivity based on ligand variations.
引用
收藏
页码：1277 / 1279
页数：3
相关论文
共 50 条
  • [1] Tunable single-site ruthenium catalysts for efficient water oxidation
    Bernet, Lucile
    Lalrempuia, Ralte
    Ghattas, Wadih
    Mueller-Bunz, Helge
    Vigara, Laura
    Llobet, Antoni
    Albrecht, Martin
    CHEMICAL COMMUNICATIONS, 2011, 47 (28) : 8058 - 8060
  • [2] Mechanism of Water Oxidation by Single-Site Ruthenium Complex Catalysts
    Concepcion, Javier J.
    Tsai, Ming-Kang
    Muckerman, James T.
    Meyer, Thomas J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (05) : 1545 - 1557
  • [3] Catalytic Mechanism of Water Oxidation with Single-Site Ruthenium-Heteropolytungstate Complexes
    Murakami, Masato
    Hong, Dachao
    Suenobu, Tomoyoshi
    Yamaguchi, Satoru
    Ogura, Takashi
    Fukuzumi, Shunichi
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (30) : 11605 - 11613
  • [4] Catalytic Water Oxidation by a Molecular Ruthenium Complex: Unexpected Generation of a Single-Site Water Oxidation Catalyst
    Rabten, Wangchuk
    Karkas, Markus D.
    Akermark, Torbjorn
    Chen, Hong
    Liao, Rong-Zhen
    Tinnis, Fredrik
    Sun, Junliang
    Siegbahn, Per E. M.
    Andersson, Pher G.
    Akermark, Bjorn
    INORGANIC CHEMISTRY, 2015, 54 (10) : 4611 - 4620
  • [5] Catalytic water oxidation by single-site catalysis
    Concepcion, Javier J.
    Jurss, Jonah W.
    Brennaman, M. Kyle
    Meyer, Thomas J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [6] Catalytic water oxidation by single-site catalysis
    Concepcion, Javier J.
    Jurss, Jonah W.
    Brennaman, M. Kyle
    Meyer, Thomas J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [7] Single-Site, Catalytic Water Oxidation on Oxide Surfaces
    Chen, Zuofeng
    Concepcion, Javier J.
    Jurss, Jonah W.
    Meyer, Thomas J.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (43) : 15580 - +
  • [8] Electronic Effects on Single-Site Iron Catalysts for Water Oxidation
    Codola, Zoel
    Garcia-Bosch, Isaac
    Acuna-Pares, Ferran
    Prat, Irene
    Luis, Josep M.
    Costas, Miquel
    Lloret-Fillol, Julio
    CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (25) : 8042 - 8047
  • [9] Single-site water oxidation catalysts and their incorporation in artificial photosynthetic devices
    Norris, Michael R.
    Concepcion, Javier J.
    Chen, Zuofeng
    Brennaman, M. Kyle
    Templeton, Joseph L.
    Meyer, Thomas J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 239
  • [10] Theoretical study of catalytic mechanism for single-site water oxidation process
    Lin, Xiangsong
    Hu, Xiangqian
    Concepcion, Javier J.
    Chen, Zuofeng
    Liu, Shubin
    Meyer, Thomas J.
    Yang, Weitao
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2012, 109 (39) : 15669 - 15672
12345