Symmetrical and difunctional substituted cobalt phthalocyanines with benzoic acids fragments: Synthesis and catalytic activity

被引：24

作者：

Vashurin, Artur ^{[1
,3
]}

Maizlish, Vladimir ^{[2
]}

Kuzmin, Ilya ^{[1
]}

Znoyko, Serafima ^{[2
]}

Morozova, Anastasiya ^{[2
]}

Razumov, Mikhail ^{[1
,3
]}

Koifman, Oscar ^{[1
]}

机构：

[1] Ivanovo State Univ Chem & Technol, Res Inst Macroheterocycles, Ivanovo 153000, Russia

[2] Ivanovo State Univ Chem & Technol, Dept Technol Fine Organ Synth, Ivanovo 153000, Russia

[3] Kazan Fed Univ, Kazan 420008, Russia

来源：

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES | 2017年 / 21卷 / 01期

基金：

俄罗斯科学基金会;

关键词：

4-bromo-5-nitro-phthalonitrile; benzoic acids; synthesis; cobalt phthalocyanines; catalysis; oxidation; HYBRID MATERIALS; OXIDATION; TETRASULFOPHTHALOCYANINE; BEHAVIOR; SILICA; CO(II);

D O I：

10.1142/S108842461750002X

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Difunctional and symmetric phthalonitriles were synthesized by nucleophilic substitution of brome and nitro-group in 4-bromo-5-nitro-phthalonitrile for residues 4-amino-, 4-hydroxyl- and 4-sulfanyl benzoic acid. Symmetrical and difunctional substituted cobalt phthalocyanines were obtained by template synthesis based on mentioned phthalonitriles. Their spectral properties and catalytic activity in aerobic oxidation of sodium N, N-carbomoditiolate were investigated.

引用

页码：37 / 47

页数：11

共 33 条

[1] Hydrogen peroxide oxidation of 2-chlorophenol and 2,4,5-trichlorophenol catalyzed by monomeric and aggregated cobalt tetrasulfophthalocyanine
Agboola, B
Ozoemena, KI
Nyokong, T
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 227 (1-2) : 209 - 216
[2] Photodynamic evaluation of tetracarboxy-phthalocyanines in model systems
Alonso, Lais
Sampaio, Renato N.
Souza, Thalita F. M.
Silva, Rodrigo C.
Barbosa Neto, Newton M.
Ribeiro, Anderson O.
Alonso, Antonio
Goncalves, Pablo J.
[J]. JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY, 2016, 161 : 100 - 107
[3] Berezin B.D., 1981, COORDINATION COMPOUN
[4] STRUCTURE AND MERCAPTAN OXIDATION ACTIVITY OF COBALT(II) PHTHALOCYANINES COVALENTLY BONDED TO SILICA OF LOW SURFACE-AREA
BUCK, T
WOHRLE, D
SCHULZEKLOFF, G
ANDREEV, A
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1991, 70 (03): : 259 - 268
[5] Synthesis and in vitro photodynamic activity of new hexadeca-carboxy phthalocyanines
Choi, CF
Tsang, PT
Huang, JD
Chan, EYM
Ko, WH
Fong, WP
Ng, DKP
[J]. CHEMICAL COMMUNICATIONS, 2004, (19) : 2236 - 2237
[6] Immobilization of metallophthalocyanines on hybrid materials and in-situ synthesis of pseudo-tubular structures from an aminofunctionalized kaolinite
da Silva, Tiago Honorato
de Souza, Thalita F. M.
Ribeiro, Anderson Orzari
Ciuffi, Katia Jorge
Nassar, Eduardo Jose
Silva, Marcio L. A.
de Faria, Emerson Henrique
Calefi, Paulo Sergio
[J]. DYES AND PIGMENTS, 2014, 100 : 17 - 23
[7] AUTOOXIDATION OF CYSTEINE CATALYZED BY COBALT(II) TETRASULFOPHTHALOCYANINE - MODELS OF OXIDASES V
DOLANSKY, J
WAGNEROVA, DM
VEPREKSISKA, J
[J]. COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1976, 41 (08) : 2326 - 2332
[8] DUBROVINA AS, 1988, ZH FIZ KHIM+, V62, P1904
[9] Dyer JR, 1965, APPL ABSORPHION SPEC
[10] Application of photoactive electrospun nanofiber materials with immobilized meso-tetraphenylporphyrin for parabens photodegradation
Gmurek, M.
Bizukojc, M.
Mosinger, J.
Ledakowicz, S.
[J]. CATALYSIS TODAY, 2015, 240 : 160 - 167

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