Synthesis and crystal structure of [C(NMe2)3]2[(CO)4Fe(μ-InCl2)2Fe(CO)4]

被引：0

作者：

Petz, W ^{[1
]}

Weller, F ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2002年 / 628卷 / 13期

关键词：

indium iron compound; ironcarbonyl; indium chloride; crystal structure;

D O I：

10.1002/1521-3749(200213)628:13<2825::AID-ZAAC2825>3.0.CO;2-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of [C(NMe2)(3)](2)[(CO)(4)FeInCl3] (1) with hot water produces the dinuclear complex [C(NMe2)(3)](2)[(CO)(4)Fe(muInCl(2))(2)Fe(CO)(4)] (2) which could be crystallized from dichloromethane/pentane. 2 crystallizes in the monoclinic space group P2(1)/n with a = 835.7(1), b = 1187.8(1), c = 1902.7(1) pm, beta = 91.877(5)degrees and Z = 2. The anion contains a four-membered Fe-In-Fe-In ring with octahedral environment at the iron atom and tetrahedral coordination at the In atom.

引用

页码：2825 / 2826

页数：2

共 14 条

[1] SYNTHESIS AND CHEMICAL CHARACTERIZATION OF SOME IN-FE HETERONUCLEAR CARBONYL-COMPOUNDS - CRYSTAL-STRUCTURE OF [NME3CH2PH]3[IN(FE(CO)4)3] AND [NET4]2[IN2BR4(MU-FE(CO)4)2] [J].

ALBANO, VG ;

CANE, M ;

IAPALUCCI, MC ;

LONGONI, G ;

MONARI, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 407 (02) :C9-C12

[2]

BOESE R, 1988, Z NATURFORSCH B, V43, P945

[3] INFRARED SPECTRA OF ISOTOPICALLY SUBSTITUTED METAL CARBONYLS .I. 13CO-SUBSTITUTED CIS-FE(CO)4I2 AND CIS-FE(CO)4BR2 [J].

BUTLER, IS ;

SPENDJIA.HK .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1969, 18 (01) :145-&

[4]

Esser M, 2000, Z ANORG ALLG CHEM, V626, P915, DOI 10.1002/(SICI)1521-3749(200004)626:4<915::AID-ZAAC915>3.3.CO

[5]

2-M

[6]

Fischer, 1999, ANGEW CHEM, V111, P3002

[7]

Fischer RA, 1999, ANGEW CHEM INT EDIT, V38, P2831

[8] PREPARATION OF [K][IN(FE2(CO)8)2](THF) AND FE2(MU-INCL(THF))2(CO)8 (THF = TETRAHYDROFURAN) [J].

LIN, CC ;

KONG, GG ;

CHO, HH ;

WHITTLESEY, BR .

INORGANIC CHEMISTRY, 1993, 32 (12) :2705-2710

[9] ON THE REACTION OF C(NME2)4 WITH BINUCLEAR TRANSITION-METAL CARBONYLS - CRYSTAL-STRUCTURES OF [C(NME2)3][MN(CO)5] AND [C(NME2)3][CO(CO)4] [J].

PETZ, W ;

WELLER, F .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1991, 46 (03) :297-302

[10]

Petz W, 2001, Z ANORG ALLG CHEM, V627, P2274, DOI 10.1002/1521-3749(200109)627:9<2274::AID-ZAAC2274>3.0.CO

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