Facile synthesis of various epitaxial and textured polymorphs of vanadium oxide thin films on the (0006)-surface of sapphire substrates

被引:20
作者
Hong, Bin [1 ]
Zhao, Jiangtao [1 ]
Hu, Kai [1 ]
Yang, Yuanjun [1 ,2 ,5 ]
Luo, Zhenlin [1 ,2 ]
Li, Xiaoguang [3 ,4 ]
Gao, Chen [1 ,2 ]
机构
[1] Univ Sci & Technol China, Collaborat Innovat Ctr Chem Energy Mat, Natl Synchrotron Radiat Lab, Hefei 230029, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Mat Sci & Engn, CAS Key Lab Mat Energy Convers, Hefei 230026, Anhui, Peoples R China
[3] Univ Sci & Technol China, Dept Phys, Hefei 230027, Anhui, Peoples R China
[4] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230027, Anhui, Peoples R China
[5] Hefei Univ Technol, Lab Quantum Mat & Interfaces, Sch Elect Sci & Appl Phys, Hefei 230009, Anhui, Peoples R China
基金
中国国家自然科学基金; 安徽省自然科学基金;
关键词
METAL-INSULATOR-TRANSITION; X-RAY-ABSORPTION; PHASE-TRANSITION; VO2; DIOXIDE; TEMPERATURE;
D O I
10.1039/c7ra00389g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Extensive attention has been paid to vanadium oxide polymorphs because of their potential to be used in applications in information and optoelectronic devices, as well as in energy harvesting technologies. However, vanadium oxides always form a very complex phase diagram; in particular, it is still challenging to synthesize pure vanadium oxide epitaxial polymorphs on low-cost, transparent and wafer-scale substrates. Here, we demonstrate the growth of epitaxial polymorphs of vanadium oxide (VO2 (R, M1 and their mixed phase), and V2O3) and (001)-textured VO2 (B) thin films on the (0006) surface of sapphire without selecting specific substrate orientations. This is achieved by controlling the vanadium arrival rate via sputtering power and oxidation of vanadium atoms through the partial pressure of oxygen using magnetron sputtering techniques, which enables wafer-scale production of the vanadium oxide thin films on the sapphire substrates. Growth phase diagrams of the various polymorphs are also developed for guiding device design based on the vanadium oxide thin films. This work paves a way towards practical applications of vanadium oxide thin films on chemically stable, transparent and low-cost sapphire substrates.
引用
收藏
页码:22341 / 22346
页数:6
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