Degradation rate quantification of solid oxide fuel cell performance with and without Al2TiO5 addition

被引:4
作者
Hunt, Clay [1 ]
Zachariasen, Marley [1 ]
Driscoll, David [1 ]
Sofie, Stephen [1 ]
Walker, Robert [2 ]
机构
[1] Montana State Univ, Dept Mech & Ind Engn, Bozeman, MT 59717 USA
[2] Montana State Univ, Dept Chem & Biochem, Bozeman, MT 59717 USA
关键词
Aluminum titanate; Modeling; Solid oxide fuel cells; Degradation rate quantification; Optimization; DOUBLE PEROVSKITES; ALUMINUM TITANATE; DEGREES-C; ANODE; SOFC; TEMPERATURE; ELECTROLYTE; MECHANISM; CATHODE; SYSTEM;
D O I
10.1016/j.ijhydene.2018.06.115
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Degradation rates of electrical current during constant voltage operation of SOFCs with anodes made using NiO precursor powders from two different manufacturers with and without the addition of aluminum titanate (ALT) added by either mechanical mixing or anode infiltration have been quantified using a novel MATLAB algorithm. Because the algorithm has been used to quantify degradation rates for many different SOFC tests, it is thought that the method can be applied to most measured SOFC data to quantify the instantaneous cell degradation rate as a function of time for the entire SOFC performance measurement. Degradation rates determined at different times have been plotted against varying concentrations of ALT addition, facilitating the estimation of optimum ALT concentration for SOFC anodes made with NiO from a specific manufacturer. The algorithm used to determine degradation rates is available upon request to the corresponding author. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:15531 / 15536
页数:6
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