Solvent-Free and Phase-Selective Synthesis of Aluminum Trimesate Metal-Organic Frameworks

被引：21

作者：

Li, Jiahong ^{[1
]}

Hurlock, Matthew J. ^{[1
]}

Goncharov, Vitaliy G. ^{[2
,3
]}

Li, Xiaoyu ^{[4
]}

Guo, Xiaofeng ^{[2
,3
]}

Zhang, Qiang ^{[1
,4
]}

机构：

[1] Washington State Univ, Dept Chem, Pullman, WA 99164 USA

[2] Washington State Univ, Dept Chem, Mat Sci & Engn Program, Pullman, WA 99164 USA

[3] Washington State Univ, Alexandra Navrotsky Inst Expt Thermodynam, Pullman, WA 99164 USA

[4] Washington State Univ, Mat Sci & Engn Program, Pullman, WA 99164 USA

来源：

INORGANIC CHEMISTRY | 2021年 / 60卷 / 07期

关键词：

MIXED-MATRIX MEMBRANES; ASSISTED SYNTHESIS; CO2; ADSORPTION; MIL-96; MOFS; SEPARATION; MICROWAVE; DEFECTS; SIZE; TRANSFORMATION;

D O I：

10.1021/acs.inorgchem.0c03598

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aluminum-based metal-organic frameworks (Al-MOFs) have shown promise as commercially valuable materials due to the variety of applications, excellent thermal, hydrothermal, and chemical stabilities, and the abundance of aluminum. In this work, for the first time, we report the solvent-free synthesis of the aluminum trimesate (Al-BTC) MOFs (MIL-100(Al), MIL-96(Al), and MIL-110(Al)) with phase selectivity and high yield. These MOFs were traditionally prepared with HF, HNO3, and bulk solvents, but these methods struggled to produce pure-phase isolations. The solvent-free strategy provides valuable insight into the future industrial scale-up production of the Al-MOFs and promotes the potential commercialization of such materials.

引用

页码：4623 / 4632

页数：10

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