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Reducing extrinsic hysteresis in first-order La(Fe,Co,Si)13 magnetocaloric systems
被引:89
作者:
Moore, J. D.
[1
]
Morrison, K.
[1
]
Sandeman, K. G.
[1
]
Katter, M.
[2
]
Cohen, L. F.
[1
]
机构:
[1] Univ London Imperial Coll Sci Technol & Med, Blackett Lab, London SW7 2AZ, England
[2] Vacuumschmelze GmbH & Co KG, D-63450 Hanau, Germany
关键词:
PHASE-TRANSITION;
LA(FEXSI1-X)(13);
GD5SI2GE2;
D O I:
10.1063/1.3276565
中图分类号:
O59 [应用物理学];
学科分类号:
摘要:
Simultaneous magnetization and sample temperature measurements were performed as a function of magnetic field and magnetic field sweep-rates to study the influence of these conditions on the hysteresis of the magnetocaloric transition in La (Fe1-x-yCoxSiy)(13) samples. The large magnetocaloric effect in the compounds that show a first-order transition cause a significant departure from isothermal conditions leading to dynamic sweep-rate dependent magnetic hysteresis. Here we show how this deleterious effect can be greatly reduced by changing the sample geometry or by use of materials which show a second-order transition only. The key signatures of nonisothermal conditions in the magnetization data are highlighted. (C) 2009 American Institute of Physics. [doi:10.1063/1.3276565]
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