Reducing extrinsic hysteresis in first-order La(Fe,Co,Si)13 magnetocaloric systems

被引:85
作者
Moore, J. D. [1 ]
Morrison, K. [1 ]
Sandeman, K. G. [1 ]
Katter, M. [2 ]
Cohen, L. F. [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Blackett Lab, London SW7 2AZ, England
[2] Vacuumschmelze GmbH & Co KG, D-63450 Hanau, Germany
关键词
PHASE-TRANSITION; LA(FEXSI1-X)(13); GD5SI2GE2;
D O I
10.1063/1.3276565
中图分类号
O59 [应用物理学];
学科分类号
摘要
Simultaneous magnetization and sample temperature measurements were performed as a function of magnetic field and magnetic field sweep-rates to study the influence of these conditions on the hysteresis of the magnetocaloric transition in La (Fe1-x-yCoxSiy)(13) samples. The large magnetocaloric effect in the compounds that show a first-order transition cause a significant departure from isothermal conditions leading to dynamic sweep-rate dependent magnetic hysteresis. Here we show how this deleterious effect can be greatly reduced by changing the sample geometry or by use of materials which show a second-order transition only. The key signatures of nonisothermal conditions in the magnetization data are highlighted. (C) 2009 American Institute of Physics. [doi:10.1063/1.3276565]
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页数:3
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共 21 条
[1]   Effect of material hysteresis in magnetic refrigeration cycles [J].
Basso, Vittorio ;
Sasso, Carlo Paolo ;
Bertotti, Giorgio ;
LoBue, Martino .
INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID, 2006, 29 (08) :1358-1365
[2]   Thermal transport properties of magnetic refrigerants La(FexSi1-x)13 and their hydrides, and Gd5Si2Ge2 and MnAs [J].
Fujieda, S ;
Hasegawa, Y ;
Fujita, A ;
Fukamichi, K .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (05) :2429-2431
[3]   Large magnetocaloric effect in La(FexSi1-x)13 itinerant-electron metamagnetic compounds [J].
Fujieda, S ;
Fujita, A ;
Fukamichi, K .
APPLIED PHYSICS LETTERS, 2002, 81 (07) :1276-1278
[4]   Comment on "Direct measurement of the 'giant' adiabatic temperature change in Gd5Si2Ge2" [J].
Gschneidner, KA ;
Pecharsky, VK ;
Brück, E ;
Duijn, HGM ;
Levin, EM .
PHYSICAL REVIEW LETTERS, 2000, 85 (19) :4190-4190
[5]   Magnetocaloric materials [J].
Gschneidner, KA ;
Pecharsky, VK .
ANNUAL REVIEW OF MATERIALS SCIENCE, 2000, 30 :387-429
[6]   Large magnetocaloric effect in melt-spun LaFe13-xSix -: art. no. 10M305 [J].
Gutfleisch, O ;
Yan, A ;
Müller, KH .
JOURNAL OF APPLIED PHYSICS, 2005, 97 (10)
[7]   Direct measurements of magnetocaloric effect in the first-order system LaFe11.7Si1.3 [J].
Hu, FX ;
Ilyn, M ;
Tishin, AM ;
Sun, JR ;
Wang, GJ ;
Chen, YF ;
Wang, F ;
Cheng, ZH ;
Shen, BG .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (09) :5503-5506
[8]   Influence of negative lattice expansion and metamagnetic transition on magnetic entropy change in the compound LaFe11.4Si1.6 [J].
Hu, FX ;
Shen, BG ;
Sun, JR ;
Cheng, ZH ;
Rao, GH ;
Zhang, XX .
APPLIED PHYSICS LETTERS, 2001, 78 (23) :3675-3677
[9]   Magnetocaloric properties of La(Fe, Co, Si) 13 bulk material prepared by powder metallurgy [J].
Katter, Matthias ;
Zellmann, Volker ;
Reppel, Georg Werner ;
Uestuener, Kaan .
IEEE Transactions on Magnetics, 2008, 44 (11 PART 2) :3044-3047
[10]   Dynamics of the magnetic field-induced first order magnetic-structural phase transformation of Gd5(Si0.5Ge0.5)4 [J].
Leib, J ;
Snyder, JE ;
Lograsso, TA ;
Schlagel, D ;
Jiles, DC .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (11) :6915-6917