Electrospray-mass spectrometric studies of selectivity of alkali metal cations extraction by calix[4]arene crowns

被引：26
|
作者：
Allain, F
Virelizier, H
Moulin, C
Jankowski, CK
Dozol, JF
Tabet, JC
机构：
[1] Univ Moncton, Dept Chim & Biochim, Moncton, NB E1A 3E9, Canada
[2] CEA Saclay, DCC, DPE, SPCP,LASO, F-91191 Gif Sur Yvette, France
[3] CEA Cadarache, DCC, DESD, SEP, F-13108 St Paul Durance, France
[4] Univ Paris 06, Lab Chim Struct Organ & Biol, UMR 7613, F-75252 Paris, France
来源：
SPECTROSCOPY-AN INTERNATIONAL JOURNAL | 2000年 / 14卷 / 03期
关键词：
calixarene crown; alkali metal cations; electrospray; complexation; selectivity;
D O I：
10.1155/2000/687809
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
Electrospray Ionization Mass Spectrometry (ESI/MS) has quickly become a versatile method of qualitative analysis of a wide variety of host-guest complexes formed in solution. However, considerable controversy exists on how ESI spectra quantitatively reflect and compare to the results obtained on these complexes. The extraction of alkali cations from acidic aqueous solutions by nine various calix[4]arenes-crown-6 diluted in NPOE, was studied by using ESI/MS. The stoichiometry of cesium complex and Cs+/Na+ selectivity were evaluated.
引用
收藏
页码：127 / 139
页数：13
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