Metallic Catalysts for Structure-Controlled Growth of Single-Walled Carbon Nanotubes

被引：61

作者：

Li, Meihui ^{[1
,2
]}

Liu, Xiyan ^{[1
]}

Zhao, Xiulan ^{[1
]}

Yang, Feng ^{[1
]}

Wang, Xiao ^{[1
]}

Li, Yan ^{[1
,2
]}

机构：

[1] Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Key Lab Phys & Chem Nanodevices, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

[2] Peking Univ, Acad Adv Interdisciplinary Studies, Beijing 100871, Peoples R China

来源：

TOPICS IN CURRENT CHEMISTRY | 2017年 / 375卷 / 02期

基金：

中国国家自然科学基金;

关键词：

Single-walled carbon nanotubes; Metallic catalyst; Chemical vapor deposition; Controlled growth; Diameter; Chirality; CHEMICAL-VAPOR-DEPOSITION; NARROW DIAMETER DISTRIBUTION; CHIRAL-SELECTIVE GROWTH; MESOPOROUS MOLECULAR-SIEVES; CO-MO CATALYSTS; IN-SITU; EPITAXIAL-GROWTH; BLOCK-COPOLYMER; HIGH-QUALITY; CVD GROWTH;

D O I：

10.1007/s41061-017-0116-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single-walled carbon nanotubes (SWNTs) have shown great potential in various applications attributed to their unique structures and outstanding structure-dependent properties. The structure-controlled growth of SWNTs is a crucial issue for their advanced applications and has been a great challenge in this field for two decades. Metal catalyst-mediated SWNT growth is believed to be very efficient. In this review, progresses in diameter and chirality controlled growth of SWNTs with metal catalysts is summarized from several aspects, including growth mechanism and theory, effects of catalysts, and the chemical vapor deposition conditions. The design, preparation, handling and dispersion, and the size evolution of metal catalysts are all discussed. The influences of growth environment including the type, composition, and pressure/concentration of the carbon source as well as the temperature on the selectivity toward the nanotube structure are analyzed. We also discuss some of the challenges and trends in this field.

引用

页数：43

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