Pinhole-free perovskite films for efficient solar modules

被引:254
作者
Qiu, W. [1 ,2 ]
Merckx, T. [1 ]
Jaysankar, M. [1 ,3 ]
de la Huerta, C. Masse [1 ]
Rakocevic, L. [1 ,3 ]
Zhang, W. [4 ]
Paetzold, U. W. [1 ]
Gehlhaar, R. [1 ]
Froyen, L. [2 ]
Poortmans, J. [1 ,3 ]
Cheyns, D. [1 ]
Snaith, H. J. [4 ]
Heremans, P. [1 ,3 ]
机构
[1] IMEC, Kapeldreef 75, B-3001 Heverlee, Belgium
[2] Katholieke Univ Leuven, MTM, Heverlee, Belgium
[3] Katholieke Univ Leuven, ESAT, Heverlee, Belgium
[4] Univ Oxford, Dept Phys, Oxford OX1 2JD, England
基金
英国工程与自然科学研究理事会;
关键词
HALIDE PEROVSKITE; SEQUENTIAL DEPOSITION; ANOMALOUS HYSTERESIS; CELLS; GROWTH; CRYSTALLIZATION; TRANSPORT; ROUTE; SIZE;
D O I
10.1039/c5ee03703d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report on a perovskite solar module with an aperture area of 4 cm(2) and geometrical fill factor of 91%. The module exhibits an aperture area power conversion efficiency (PCE) of 13.6% from a current-voltage scan and 12.6% after 5 min of maximum power point tracking. High PCE originates in pinhole-free perovskite films made with a precursor combination of Pb(CH3CO2)(2)center dot 3H(2)O, PbCl2, and CH3NH3I.
引用
收藏
页码:484 / 489
页数:6
相关论文
共 40 条
[1]   Highly Reproducible Perovskite Solar Cells with Average Efficiency of 18.3% and Best Efficiency of 19.7% Fabricated via Lewis Base Adduct of Lead(II) Iodide [J].
Ahn, Namyoung ;
Son, Dae-Yong ;
Jang, In-Hyuk ;
Kang, Seong Min ;
Choi, Mansoo ;
Park, Nam-Gyu .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (27) :8696-8699
[2]  
[Anonymous], ACS NANO
[3]   Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells [J].
Bi, Cheng ;
Wang, Qi ;
Shao, Yuchuan ;
Yuan, Yongbo ;
Xiao, Zhengguo ;
Huang, Jinsong .
NATURE COMMUNICATIONS, 2015, 6
[4]   Sequential deposition as a route to high-performance perovskite-sensitized solar cells [J].
Burschka, Julian ;
Pellet, Norman ;
Moon, Soo-Jin ;
Humphry-Baker, Robin ;
Gao, Peng ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
NATURE, 2013, 499 (7458) :316-+
[5]   The optoelectronic role of chlorine in CH3NH3PbI3(Cl)-based perovskite solar cells [J].
Chen, Qi ;
Zhou, Huanping ;
Fang, Yihao ;
Stieg, Adam Z. ;
Song, Tze-Bin ;
Wang, Hsin-Hua ;
Xu, Xiaobao ;
Liu, Yongsheng ;
Lu, Shirong ;
You, Jingbi ;
Sun, Pengyu ;
Mckay, Jeff ;
Goorsky, Mark S. ;
Yang, Yang .
NATURE COMMUNICATIONS, 2015, 6
[6]   Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process [J].
Chen, Qi ;
Zhou, Huanping ;
Hong, Ziruo ;
Luo, Song ;
Duan, Hsin-Sheng ;
Wang, Hsin-Hua ;
Liu, Yongsheng ;
Li, Gang ;
Yang, Yang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (02) :622-625
[7]   Efficient and stable large-area perovskite solar cells with inorganic charge extraction layers [J].
Chen, Wei ;
Wu, Yongzhen ;
Yue, Youfeng ;
Liu, Jian ;
Zhang, Wenjun ;
Yang, Xudong ;
Chen, Han ;
Bi, Enbing ;
Ashraful, Islam ;
Graetzel, Michael ;
Han, Liyuan .
SCIENCE, 2015, 350 (6263) :944-948
[8]   MAPbl3-x Clx Mixed Halide Perovskite for Hybrid Solar Cells: The Role of Chloride as Dopant on the Transport and Structural Properties [J].
Colella, Silvia ;
Mosconi, Edoardo ;
Fedeli, Paolo ;
Listorti, Andrea ;
Gazza, Francesco ;
Orlandi, Fabio ;
Ferro, Patrizia ;
Besagni, Tullo ;
Rizzo, Aurora ;
Calestani, Gianluca ;
Gigli, Giuseppe ;
De Angelis, Filippo ;
Mosca, Roberto .
CHEMISTRY OF MATERIALS, 2013, 25 (22) :4613-4618
[9]   Impact of microstructure on local carrier lifetime in perovskite solar cells [J].
deQuilettes, Dane W. ;
Vorpahl, Sarah M. ;
Stranks, Samuel D. ;
Nagaoka, Hirokazu ;
Eperon, Giles E. ;
Ziffer, Mark E. ;
Snaith, Henry J. ;
Ginger, David S. .
SCIENCE, 2015, 348 (6235) :683-686
[10]   Flexible Perovskite Photovoltaic Modules and Solar Cells Based on Atomic Layer Deposited Compact Layers and UV-Irradiated TiO2 Scaffolds on Plastic Substrates [J].
Di Giacomo, Francesco ;
Zardetto, Valerio ;
D'Epifanio, Alessandra ;
Pescetelli, Sara ;
Matteocci, Fabio ;
Razza, Stefano ;
Di Carlo, Aldo ;
Licoccia, Silvia ;
Kessels, Wilhelmus M. M. ;
Creatore, Mariadriana ;
Brown, Thomas M. .
ADVANCED ENERGY MATERIALS, 2015, 5 (08)