Ru3(CO)12-Catalyzed Carbonylation of C-H Bonds by Triazole-Directed C-H Activation

被引：13
|
作者：
Haito, Akira [1 ]
Yamaguchi, Mao [1 ]
Chatani, Naoto [1 ]
机构：
[1] Osaka Univ, Dept Appl Chem, Fac Engn, Suita, Osaka 5650871, Japan
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 7卷 / 07期
关键词：
carbonylation; C-H activation; chelation; ruthenium; triazole; RUTHENIUM-CATALYZED CARBONYLATION; DIRECT ARYLATIONS; BENZENE-RING; HETEROAROMATIC-COMPOUNDS; CLICK CHEMISTRY; ORTHO-ACYLATION; ARENES; 1,2,3-TRIAZOLES; ACYLOXYLATION; HALOGENATION;
D O I：
10.1002/ajoc.201800182
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Ru-catalyzed carbonylation of C-H bonds directed by a triazole ring is reported. The reaction involves a three-component coupling reaction of a C-H bond, carbon monoxide (CO), and ethylene, leading to the production of a ketone as the carbonylation product.
引用
收藏
页码：1315 / 1318
页数：4
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