Functionalized Carbon Nanotube and MnO2 Nanoflower Hybrid as an Electrode Material for Supercapacitor Application

被引:13
作者
Mothkuri, Sagar [1 ]
Gupta, Honey [1 ]
Jain, Pawan K. [1 ]
Rao, Tata Narsinga [1 ]
Padmanabham, Gade [1 ]
Chakrabarti, Supriya [1 ,2 ]
机构
[1] Int Adv Res Ctr Powder Met & New Mat, Ctr Carbon Mat, Hyderabad 500005, Telangana, India
[2] Ulster Univ, Sch Engn, Nanotechnol & Integrated Bioengn Ctr NIBEC, Newtownabbey BT37 0QB, North Ireland
关键词
FCNT-MnO2; hydrothermal; supercapacitor; specific energy; specific power; HYDROTHERMAL SYNTHESIS; CONTROLLABLE SYNTHESIS; ALPHA-MNO2; ENERGY; PSEUDOCAPACITANCE; NANOCOMPOSITE; PERFORMANCE; FABRICATION; CONVERSION; NANORODS;
D O I
10.3390/mi12020213
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Functionalized carbon nanotube (FCNT) and Manganese Oxide (MnO2) nanoflower hybrid material was synthesized using hydrothermal technique as a promising electrode material for supercapacitor applications. The morphological investigation revealed the formation of 'nanoflower' like structure of MnO2 connected with FCNT, thus paving an easy path for the conduction of electrons during the electrochemical mechanism. A significant improvement in capacitance properties was observed in the hybrid material, in which carbon nanotube acts as a conducting cylindrical path, while the major role of MnO2 was to store the charge, acting as an electrolyte reservoir leading to an overall improved electrochemical performance. The full cell electrochemical analysis of FCNT-MnO2 hybrid using 3 M potassium hydroxide (KOH) electrolyte indicated a specific capacitance of 359.53 F g(-1), specific energy of 49.93 Wh kg(-1) and maximum specific power of 898.84 W kg(-1) at 5 mV s(-1). The results show promise for the future of supercapacitor development based on hybrid electrode materials, where high specific energy can be achieved along with high specific power and long cycle life.
引用
收藏
页数:16
相关论文
共 50 条
  • [41] Fiber-based MnO2/carbon nanotube/polyimide asymmetric supercapacitor
    Huang, Guangxi
    Zhang, Ye
    Wang, Lie
    Sheng, Peng
    Peng, Huisheng
    CARBON, 2017, 125 : 595 - 604
  • [42] Structural supercapacitor electrodes for energy storage by electroless deposition of MnO2 on carbon nanotube mats
    Tynan, Benjamin
    Zhou, Yang
    Brown, Sonya A.
    Dai, Liming
    Rider, Andrew N.
    Wang, Chun H.
    COMPOSITES SCIENCE AND TECHNOLOGY, 2023, 238
  • [43] Structural evolution of multi-walled carbon nanotube/MnO2 composites as supercapacitor electrodes
    Li, Qiang
    Anderson, Jordan M.
    Chen, Yiqing
    Zhai, Lei
    ELECTROCHIMICA ACTA, 2012, 59 : 548 - 557
  • [44] RGO/MnO2/polypyrrole ternary film electrode for supercapacitor
    Zhou, Haiyan
    Yan, Zhe
    Yang, Xing
    Lv, Jing
    Kang, Liping
    Liu, Zong-Huai
    MATERIALS CHEMISTRY AND PHYSICS, 2016, 177 : 40 - 47
  • [45] MnO2/polyaniline hybrid nanostructures on carbon cloth for supercapacitor electrodes
    He, Ying
    Du, Shuangshuang
    Li, Huailong
    Cheng, Qilin
    Pavlinek, Vladimir
    Saha, Petr
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2016, 20 (05) : 1459 - 1467
  • [46] MnO2/PVP/MWCNT hybrid nano composites as electrode materials for high performance supercapacitor
    Jaggi, Neena
    Sharma, Deepa
    Sharma, Priya
    MATERIALS RESEARCH EXPRESS, 2016, 3 (10):
  • [47] Electrochemical Performance of α-MnO2 Nanorods/Activated Carbon Hybrid Supercapacitor
    Aravindan, V.
    Reddy, M. V.
    Madhavi, S.
    Rao, G. V. Subba
    Chowdari, B. V. R.
    NANOSCIENCE AND NANOTECHNOLOGY LETTERS, 2012, 4 (07) : 724 - 728
  • [48] MnO2/polyaniline hybrid nanostructures on carbon cloth for supercapacitor electrodes
    Ying He
    Shuangshuang Du
    Huailong Li
    Qilin Cheng
    Vladimir Pavlinek
    Petr Saha
    Journal of Solid State Electrochemistry, 2016, 20 : 1459 - 1467
  • [49] Novel graphene based MnO2/polyaniline nanohybrid material for efficient supercapacitor application
    Tale, Bhagyashri U.
    Nemade, Kailash R.
    Tekade, Pradip V.
    JOURNAL OF POROUS MATERIALS, 2024, 31 (06) : 2053 - 2065
  • [50] Facile synthesis of tremella-like MnO2 and its application as supercapacitor electrodes
    Ren, Xiangcang
    Tian, Chuanjin
    Li, Sa
    Zhao, Yucheng
    Wang, Chang-An
    FRONTIERS OF MATERIALS SCIENCE, 2015, 9 (03) : 234 - 240