The vibrational spectrum of the MnO2- and MnO4- anions in solid argon

被引：0
作者：
Dong, H
Wang, Y
Zhou, MF [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Fudan Univ, Laser Chem Inst, Shanghai 200433, Peoples R China
来源：
CHEMICAL PHYSICS LETTERS | 2002年 / 364卷 / 5-6期
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Laser-ablated manganese atoms react with oxygen in excess argon on condensation to form the neutral MnO and MnO2 oxide molecules as the major products. The MnO2 anions were produced via capture of ablated electrons by the neutral molecules. On annealing, the MnO4- anions were also formed and identified based on isotopic substitutions as well as density functional frequency calculations. Doping with CCl4 to serve as an electron trap gave the same neutral absorptions and virtually eliminated the anion absorptions, which strongly supports the anion identification. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码：511 / 516
页数：6
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