Amperometric detection of H2O2 using gold electrodes modified with Starburst PAMAM dendrimers and Prussian Blue

被引:15
作者
Bustos, Erika Bustos
Chapman, Thomas W.
Rodriguez-Valadez, F.
Godinez, Luis A.
机构
[1] Ctr Invest & Desarrollo Tecnol Electroquim SC, Electrochem Dept, Queretaro 76700, Mexico
[2] Univ Wisconsin, Dept Chem Engn, Madison, WI 53706 USA
关键词
chemically modified electrodes; Prussian Blue; PAMAM dendrimers; hydrogen peroxide; electrochemical sensors;
D O I
10.1002/elan.200603619
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Gold-bead electrodes were modified by covalent bonding or physical adsorption of several Starburst PAMAM dendrimers (generations 2.0, 3.0 and 4.0) followed by absorption of Prussian Blue (PB). The covalent dendrimer-PB-modified electrodes can be used as amperometric sensors of H2O2 in aqueous solution. They offer enhanced sensitivity with correspondingly lower detection and quantification limits compared to similar amperometric detectors.
引用
收藏
页码:2092 / 2098
页数:7
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