Pyrolysis of solid fuels: Thermochemical behaviour, kinetics and compensation effect

被引：59

作者：

Czajka, Krzysztof ^{[1
]}

Kisiela, Anna ^{[1
]}

Moron, Wojciech ^{[1
]}

Ferens, Wieslaw ^{[1
]}

Rybak, Wieslaw ^{[1
]}

机构：

[1] Wroclaw Univ Technol, Fac Mech & Power Engn, PL-50370 Wroclaw, Poland

来源：

FUEL PROCESSING TECHNOLOGY | 2016年 / 142卷

关键词：

Devolatilization; TGA; DAEM; Thermal lag; Biomass; Coal; ACTIVATION-ENERGY MODEL; THERMAL-DECOMPOSITION; TG-FTIR; THERMOGRAVIMETRIC ANALYSIS; DEVOLATILIZATION KINETICS; SEWAGE-SLUDGE; BIOMASS; COAL; WOOD; PARAMETERS;

D O I：

10.1016/j.fuproc.2015.09.027

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The paper presents the pyrolysis behaviour of eleven different rank solid fuels, carried out using thermogravimetry (TG). Obtained experimental curves were compared with profiles determined using the Single First Order Reaction (SFOR) model and three different approaches of Distributed Activation Energy Model (DAEM). The aim of this work was to develop different models dedicated to pyrolysis, in particular further investigate the interrelation between the activation energy and the pre-exponential factor, its impact on the results quality and attribution with the fuel properties and pyrolysis mechanism. Obtained results showed that the compensation effect, often noted for SFOR, has also occurred for DAEM. Furthermore, analysis indicated an existence of a relationship between the characteristic temperature T-iso (and ln(k(iso))) and fuel properties. Observed interrelation may be attributed to the change in reaction mechanism. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：42 / 53

页数：12

共 65 条

[1] Pyrolysis kinetics of olive residue/plastic mixtures by non-isothermal thermogravimetry [J].

Aboulkas, A. ;

El Harhi, K. ;

El Bouadili, A. ;

Nadifiyine, M. ;

Benchanaa, M. ;

Mokhlisse, A. .

FUEL PROCESSING TECHNOLOGY, 2009, 90 (05) :722-728

[2] Non-isothermal kinetic analysis of the devolatilization of corn cobs and sugar cane bagasse in an inert atmosphere [J].

Aboyade, Akinwale O. ;

Hugo, Thomas J. ;

Carrier, Marion ;

Meyer, Edson L. ;

Stahl, Ralph ;

Knoetze, Johannes H. ;

Goergens, Johann F. .

THERMOCHIMICA ACTA, 2011, 517 (1-2) :81-89

[3] COMPENSATION EFFECT IN THE PYROLYSIS OF CELLULOSIC MATERIALS [J].

AGRAWAL, RK .

THERMOCHIMICA ACTA, 1985, 90 (AUG) :347-351

[4] THE COMPENSATION EFFECT - A FACT OR A FICTION [J].

AGRAWAL, RK .

JOURNAL OF THERMAL ANALYSIS, 1989, 35 (03) :909-917

[5]

[Anonymous], THESIS

[6] KINETICS OF CELLULOSE PYROLYSIS IN NITROGEN AND STEAM [J].

ANTAL, MJ ;

FRIEDMAN, HL ;

ROGERS, FE .

COMBUSTION SCIENCE AND TECHNOLOGY, 1980, 21 (3-4) :141-152

[7] COAL DEVOLATILIZATION AND HYDROGASIFICATION [J].

ANTHONY, DB ;

HOWARD, JB .

AICHE JOURNAL, 1976, 22 (04) :625-656

[8] A comparison of different methods for predicting coal devolatilisation kinetics [J].

Arenillas, A ;

Rubiera, F ;

Pevida, C ;

Pis, JJ .

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2001, 58 :685-701

[9] KINETICS OF THERMAL DECOMPOSITION OF PULVERIZED COAL PARTICLES [J].

BADZIOCH, S ;

HAWKSLEY, PG .

INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1970, 9 (04) :521-&

[10] Kinetic study of solid waste pyrolysis using distributed activation energy model [J].

Bhavanam, Anjireddy ;

Sastry, R. C. .

BIORESOURCE TECHNOLOGY, 2015, 178 :126-131

← 1 2 3 4 5 6 7 →