The structure of the blue luminescent δ-phase of tris(8-hydroxyquinoline)aluminium(III) (Alq3)

被引：139
|
作者：
Cölle, M
Dinnebier, RE
Brütting, W
机构：
[1] Univ Bayreuth, D-95440 Bayreuth, Germany
[2] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 23期
关键词：
D O I：
10.1039/b209164j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The existence of the facial isomer in the delta-phase of Alq(3) is proven by X-ray structural analysis, revealing that both the different molecular structure and the weaker overlap of the pi-orbitals of hydroxyquinoline ligands belonging to neighboring Alq(3) molecules as compared to other phases (alpha,beta) are likely to be the origin of the significantly different optical properties of delta-Alq(3).
引用
收藏
页码：2908 / 2909
页数：2
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