A new open-framework fluorinated gallium phosphate with large 18-ring channels (MIL-31)

被引：80
作者：
Sassoye, C
Loiseau, T
Taulelle, F
Férey, G
机构：
[1] Univ Versailles, Inst Lavoisier, CNRS, UMR 8637, F-78035 Versailles, France
[2] Univ Strasbourg 1, Inst Le Bel, Lab RMN & Chim Solide, UMR Bruker CNRS ULP 7510, F-67070 Strasbourg, France
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 11期
关键词：
D O I：
10.1039/b001948h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new open-framework fluorinated gallium phosphate (MIL-31) containing the Ga-9(PO4)(9)(H2O)(OH)(OH,F)(4)(5-) anion was hydrothermally synthesized by using long alkyl chain diamines (C-9 and C-10) as structure-directing agents; its crystal structure is built up from hexameric units and exhibits large one-dimensional hexagonal channels delimited by 18-rings.
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页码：943 / 944
页数：2
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