SBA-15 as a Support for Effective Olefin Metathesis Catalysts

被引：14

作者：

Balcar, Hynek ^{[1
]}

Cejka, Jiri ^{[2
]}

机构：

[1] Czech Acad Sci, J Heyrovsky Inst Phys Chem, Vvi, Dolejskova 3, Prague 18223 8, Czech Republic

[2] Charles Univ Prague, Fac Sci, Dept Phys & Macromol Chem, Hlavova 2030-8, Prague 12843, Czech Republic

来源：

CATALYSTS | 2019年 / 9卷 / 09期

关键词：

olefin metathesis; SBA-15; mesoporous molecular sieve; Mo and Ru hybrid catalysts; MESOPOROUS MOLECULAR-SIEVES; HOVEYDA-GRUBBS; THEORETICAL INVESTIGATIONS; HETEROGENEOUS CATALYSTS; 2-DIMENSIONAL ZEOLITES; ALKYLIDENE COMPLEXES; RUTHENIUM CARBENES; PORE-SIZE; SILICA; TUNGSTEN;

D O I：

10.3390/catal9090743

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Olefin metathesis is the catalytic transformation of olefinic substrates, finding a wide range of applications in organic synthesis. The mesoporous molecular sieve Santa Barbara Amorphous (SBA-15) has proven to be an excellent support for metathesis catalysts thanks to its regular mesoporous structure, high BET area, and large pore volume. A survey of catalysts consisting of (i) molybdenum and tungsten oxides on SBA-15, and (ii) molybdenum and ruthenium organometallic complexes (Schrock and Grubbs-type carbenes) on SBA-15 is provided together with their characterization and catalytic performance in various metathesis reactions. The comparison with catalysts based on other supports demonstrates the high quality of the mesoporous molecular sieve SBA-15 as an advanced catalyst support.

引用

页数：18

共 90 条

[1]

Allen D.P., 2015, HDB METATHESIS, V1, P97

[2] How Strain Affects the Reactivity of Surface Metal Oxide Catalysts [J].

Amakawa, Kazuhiko ;

Sun, Lili ;

Guo, Chunsheng ;

Haevecker, Michael ;

Kube, Pierre ;

Wachs, Israel E. ;

Lwin, Soe ;

Frenkel, Anatoly I. ;

Patlolla, Anitha ;

Hermann, Klaus ;

Schloegl, Robert ;

Trunschke, Annette .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (51) :13553-13557

[3] In Situ Generation of Active Sites in Olefin Metathesis [J].

Amakawa, Kazuhiko ;

Wrabetz, Sabine ;

Kroehnert, Jutta ;

Tzolova-Mueller, Genka ;

Schloegl, Robert ;

Trunschke, Annette .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (28) :11462-11473

[4] Mesoporous molecular sieves as advanced supports for olefin metathesis catalysts [J].

Balcar, H. ;

Cejka, J. .

COORDINATION CHEMISTRY REVIEWS, 2013, 257 (21-22) :3107-3124

[5] MCM-41 anchored Schrock catalyst Mo(=CHCMe2Ph)(=N-2,6-i-Pr2C6H3)[OCMe(CF3)2]2-activity in 1-heptene metathesis and cross-metathesis reactions [J].

Balcar, H ;

Zilková, N ;

Sedlácek, J ;

Zedník, J .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 232 (1-2) :53-58

[6]

Balcar H., 2013, NEW FUTURE DEV CATAL, P1

[7] MoO3 on zeolites MCM-22, MCM-56 and 2D-MFI as catalysts for 1-octene metathesis [J].

Balcar, Hynek ;

Kubu, Martin ;

Zilkova, Nadezda ;

Shamzhy, Mariya .

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2018, 14 :2931-2939

[8] Metathesis of cardanol over ammonium tagged Hoveyda-Grubbs type catalyst supported on SBA-15 [J].

Balcar, Hynek ;

Zilkova, Nadezda ;

Kubu, Martin ;

Polasek, Miroslav ;

Zednik, Jiri .

CATALYSIS TODAY, 2018, 304 :127-134

[9] Ru complexes of Hoveyda-Grubbs type immobilized on lamellar zeolites: activity in olefin metathesis reactions [J].

Balcar, Hynek ;

Zilkova, Nadezda ;

Kubu, Martin ;

Mazur, Michal ;

Bastl, Zdenek ;

Cejka, Jiri .

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2015, 11 :2087-2096

[10] Hoveyda-Grubbs type metathesis catalyst immobilized on mesoporous molecular sieves MCM-41 and SBA-15 [J].

Balcar, Hynek ;

Shinde, Tushar ;

Zilkova, Nadezda ;

Bastl, Zdenek .

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2011, 7 :22-28

← 1 2 3 4 5 6 7 8 9 →