One-pot, three-component Mannich-type reaction catalyzed by functionalized ionic liquid

被引：29

作者：

Fang, Dong ^{[1
,2
]}

Gong, Kai ^{[2
]}

Zhang, Dai-zhen ^{[1
]}

Liu, Zu-liang ^{[1
,2
]}

机构：

[1] Jiangsu Prov Key Lab Coast Wetland Bioresource &, Yancheng 224002, Peoples R China

[2] Nanjing Univ Sci & Technol, Sch Chem Engn, Nanjing 210094, Peoples R China

来源：

MONATSHEFTE FUR CHEMIE | 2009年 / 140卷 / 11期

关键词：

Mannich-type reaction; Ionic liquid; Catalyst; One-pot reaction; AROMATIC-ALDEHYDES; ANILINES; KETONES;

D O I：

10.1007/s00706-009-0182-y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A three-component Mannich-type reaction of aromatic aldehydes, aromatic amines, and ketones was catalyzed by a novel functionalized ionic liquid, 3-(N,N-dimethyldodecylammonium)propanesulfonic acid hydrogen sulfate ([DDPA][HSO4]) at room temperature to give various beta-amino carbonyl compounds in good yields. The catalyst could be reused at least six times without noticeably reducing catalytic activity.

引用

页码：1325 / 1329

页数：5

共 31 条

[1]

[Anonymous], CHIN J SW NORM U

[2]

Arend M, 1998, ANGEW CHEM INT EDIT, V37, P1044, DOI 10.1002/(SICI)1521-3773(19980504)37:8<1044::AID-ANIE1044>3.0.CO

[3]

2-E

[4] The direct catalytic asymmetric Mannich reaction [J].

Córdova, A .

ACCOUNTS OF CHEMICAL RESEARCH, 2004, 37 (02) :102-112

[5] One-pot green procedure for Biginelli reaction catalyzed by novel task-specific room-temperature ionic liquids [J].

Dong, Fang ;

Jun, Luo ;

Xinli, Zhou ;

Zhiwen, Ye ;

Zuliang, Liu .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 274 (1-2) :208-211

[6] Mannich reaction in water using acidic ionic liquid as recoverable and reusable catalyst [J].

Dong, Fang ;

Jun, Luo ;

Zhou Xin-Li ;

Liu Zu-Liang .

CATALYSIS LETTERS, 2007, 116 (1-2) :76-80

[7] Regioselective mononitration of aromatic compounds using Bronsted acidic ionic liquids as recoverable catalysts [J].

Fang, Dong ;

Shi, Qun-Rong ;

Cheng, Jian ;

Gong, Kai ;

Liu, Zu-Liang .

APPLIED CATALYSIS A-GENERAL, 2008, 345 (02) :158-163

[8] Brlnsted acidic ionic liquids and their use as dual solvent-catalysts for Fischer esterifications [J].

Fang, Dong ;

Zhou, Xin-Li ;

Ye, Zhi-Wen ;

Liu, Zu-Liang .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (24) :7982-7984

[9] Catalysed esterifications in room temperature ionic liquids with acidic counteranion as recyclable reaction media [J].

Fraga-Dubreuil, J ;

Bourahla, K ;

Rahmouni, M ;

Bazureau, JP ;

Hamelin, J .

CATALYSIS COMMUNICATIONS, 2002, 3 (05) :185-190

[10] Biodegradable ionic liquids - Part II. Effect of the anion and toxicology [J].

Garcia, MT ;

Gathergood, N ;

Scammells, PJ .

GREEN CHEMISTRY, 2005, 7 (01) :9-14

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