A tetraphosphorus ligand for highly regioselective isomerization-hydroformylation of internal olefins

被引：111

作者：

Yan, Yongjun ^{[1
]}

Zhang, Xiaowei ^{[1
]}

Zhang, Xumu ^{[1
]}

机构：

[1] Penn State Univ, Dept Chem, University Pk, PA 16802 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 50期

关键词：

D O I：

10.1021/ja0622249

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new pyrrole-based tetraphosphorus ligand capable of forming multiple chelating modes has been prepared. Higher regioselectivity has been achieved in the rhodium-catalyzed isomerization-hydroformylations of internal olefins compared with its bisphosphorus analogue.

引用

页码：16058 / 16061

页数：4

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