A tetraphosphorus ligand for highly regioselective isomerization-hydroformylation of internal olefins

被引：109
|
作者：
Yan, Yongjun [1 ]
Zhang, Xiaowei [1 ]
Zhang, Xumu [1 ]
机构：
[1] Penn State Univ, Dept Chem, University Pk, PA 16802 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 50期
关键词：
D O I：
10.1021/ja0622249
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new pyrrole-based tetraphosphorus ligand capable of forming multiple chelating modes has been prepared. Higher regioselectivity has been achieved in the rhodium-catalyzed isomerization-hydroformylations of internal olefins compared with its bisphosphorus analogue.
引用
收藏
页码：16058 / 16061
页数：4
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