Formation of CuI(CH3CN)4ClO4 in the Reactions of Copper(II) Perchlorate with Acetonitrile in the Presence of Sulfur-Containing Organic Compounds

被引：10

作者：

Beloglazkina, E. K. ^{[1
]}

Shimorsky, A. V. ^{[1
]}

Mazhuga, A. G. ^{[1
]}

Shilova, O. V. ^{[1
]}

Tafeenko, V. A. ^{[1
]}

Zyk, N. V. ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119992, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2009年 / 79卷 / 07期

关键词：

LIGAND INVOLVING SULFIDES; X-RAY-STRUCTURE; DICOPPER COMPLEXES; CRYSTAL-STRUCTURE; REDUCTION; BENZIMIDAZOLES; RESOLUTION;

D O I：

10.1134/S1070363209070172

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cu(ClO4)(2)center dot 6H(2)O was shown to react with 2,2'-[propane-1,3-diylbis(thio-2-phenylnemethylidene]-bis(3-pyridylamine) (1) or (5Z)-2-ethoxycarbonylmethyl-(2-pyridylmethylidene)-3,5-dihydro-4H-imidazol-4-one (II) in the presence of CH3CN with the reduction of copper(II) to copper(l) and the formation of the tetrahedral complex Cu-I(CH3CN)(4)ClO4 (III). In the course of the reaction the organic ligands I and If were oxidized to the corresponding sulfoxides.

引用

页码：1504 / 1508

页数：5

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