Polymerization of bisphenol a using Coprinus cinereus peroxidase (CiP) and its application as a photoresist resin

被引：28
作者：
Kim, Yong Hwan [1 ]
An, Eun Suk [1 ]
Park, Seung Young [1 ]
Lee, Jeong-O [1 ]
Kim, Ji Hyun [1 ]
Song, Bong Keun [1 ]
机构：
[1] Kwangwoon Univ, Dept Chem Engn, Seoul 139701, South Korea
来源：
JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC | 2007年 / 44卷 / 3-4期
关键词：
photoresist; bisphenol A; enzymatic polymerization; Coprinus cinereus peroxidase;
D O I：
10.1016/j.molcatb.2006.10.004
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Bisphenol A was polymerized by Coprinus cinereus peroxidase in aqueous 2-propanol solution. Various polymerized products with different molecular weights and hydroxyl values were synthesized depending on the reaction compositions (the ratio of aqueous buffer to 2-propanol). Poly(bisphenol A), a polymer of bisphenol A, was mixed with a diazonaphthoquinone derivative to form a new type of photoresist. A thin photoresist film was formed on the silicon wafer and exposed to UV light for different lengths of time. Poly(bisphenol A) having a molecular weight of approximately 3000 yielded sharply contrasted patterns as compared with the other poly(bisphenol A)s having different molecular weights. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：149 / 154
页数：6
相关论文
共 14 条
  • [1] Enzyme-based molecular imprinting with metals
    Cui, A
    Singh, A
    Kaplan, DL
    [J]. BIOMACROMOLECULES, 2002, 3 (06) : 1353 - 1358
  • [2] HONDA K, 1992, P SOC PHOTO-OPT INS, V1672, P297, DOI 10.1117/12.59760
  • [3] Inactivation of horseradish peroxidase by phenoxyl radical attack
    Huang, Q
    Huang, QG
    Pinto, RA
    Griebenow, K
    Schweitzer-Stenner, R
    Weber, WJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (05) : 1431 - 1437
  • [4] Precipitation of enzyme-catalyzed phenol oxidative coupling products: Background ion and pH effects
    Huang, QG
    Tang, JX
    Weber, WJ
    [J]. WATER RESEARCH, 2005, 39 (13) : 3021 - 3027
  • [5] Transformation and removal of bisphenol A from aqueous phase via peroxidase-mediated oxidative coupling reactions: Efficacy, products, and pathways
    Huang, QG
    Weber, WJ
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (16) : 6029 - 6036
  • [6] *INF NETW, 2006, LCD MARK TECHN DIR M
  • [7] New positive-type photoresists based on enzymatically synthesized polyphenols
    Kadota, J
    Fukuoka, T
    Uyama, H
    Hasegawa, K
    Kobayashi, S
    [J]. MACROMOLECULAR RAPID COMMUNICATIONS, 2004, 25 (02) : 441 - 444
  • [8] Synthesis of polycardanol from a renewable resource using a fungal peroxidase from Coprinus cinereus
    Kim, YH
    Won, KH
    Kwon, JM
    Jeong, HS
    Park, SY
    An, ES
    Song, BK
    [J]. JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2005, 34 (1-6) : 33 - 38
  • [9] Laccase-catalyzed oxidative polymerization of phenols
    Mita, N
    Tawaki, S
    Uyama, H
    Kobayashi, S
    [J]. MACROMOLECULAR BIOSCIENCE, 2003, 3 (05) : 253 - 257
  • [10] Structural control in enzymatic oxidative polymerization of phenols with varying the solvent and substituent nature
    Mita, N
    Tawaki, S
    Uyama, H
    Kobayashi, S
    [J]. CHEMISTRY LETTERS, 2002, (03) : 402 - 403
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