Highly Selective CO2 Capture in Flexible 3D Coordination Polymer Networks

被引：359

作者：

Choi, Hye-Sun ^{[1
]}

Suh, Myunghyun Paik ^{[1
]}

机构：

[1] Seoul Natl Univ, Dept Chem, Seoul 151747, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 37期

关键词：

adsorption; carbon dioxide capture; macrocyclic complexes; nickel; organic-inorganic hybrid composites; METAL-ORGANIC FRAMEWORK; ZEOLITIC IMIDAZOLATE FRAMEWORKS; SINGLE-CRYSTAL TRANSFORMATIONS; ION-EXCHANGE PROPERTIES; BILAYER OPEN FRAMEWORK; CARBON-DIOXIDE; PALLADIUM NANOPARTICLES; ADSORPTION SELECTIVITY; MACROCYCLIC COMPLEXES; SORPTION PROPERTIES;

D O I：

10.1002/anie.200902836

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Keeping limber: Three-dimensional coordination polymers incorporating flexible pillars (see picture, left) exhibit highly selective adsorption of CO2 over N2, H2, and CH4 (see picture, right), thermal stability up to 300 °C, as well as air and water stability, and allow efficient CO2 capture, storage, and sensing. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6865 / 6869

页数：5

共 58 条

[1]

[Anonymous], 2009, ANGEW CHEM

[2] Carborane-based metal-organic frameworks as highly selective sorbents for CO2 over methane [J].

Bae, Youn-Sang ;

Farha, Omar K. ;

Spokoyny, Alexander M. ;

Mirkin, Chad A. ;

Hupp, Joseph T. ;

Snurr, Randall Q. .

CHEMICAL COMMUNICATIONS, 2008, (35) :4135-4137

[3] High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture [J].

Banerjee, Rahul ;

Phan, Anh ;

Wang, Bo ;

Knobler, Carolyn ;

Furukawa, Hiroyasu ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2008, 319 (5865) :939-943

[4] Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties [J].

Banerjee, Rahul ;

Furukawa, Hiroyasu ;

Britt, David ;

Knobler, Carolyn ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (11) :3875-+

[5] A microporous metal-organic framework for separation of CO2/N2 and CO2/CH4 by fixed-bed adsorption [J].

Bastin, Laurent ;

Barcia, Patrick S. ;

Hurtado, Eric J. ;

Silva, Jose A. C. ;

Rodrigues, Alirio E. ;

Chen, Banglin .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (05) :1575-1581

[6] Metal-organic frameworks with high capacity and selectivity for harmful gases [J].

Britt, David ;

Tranchemontagne, David ;

Yaghi, Omar M. .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2008, 105 (33) :11623-11627

[7]

Chen B., 2005, ANGEW CHEM, V117, P4823, DOI DOI 10.1002/ange.200462787

[8] A microporous metal-organic framework for gas-chromatographic separation of alkanes [J].

Chen, BL ;

Liang, CD ;

Yang, J ;

Contreras, DS ;

Clancy, YL ;

Lobkovsky, EB ;

Yaghi, OM ;

Dai, S .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) :1390-1393

[9]

CHEN BL, 2006, ANGEW CHEM INT ED, V0118

[10] High H2 adsorption in a microporous metal-organic framework with open metal sites [J].

Chen, BL ;

Ockwig, NW ;

Millward, AR ;

Contreras, DS ;

Yaghi, OM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (30) :4745-4749

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