Preparation of highly oriented copper phthalocyanine film by molecular templating effects for organic field-effect transistor

被引:18
作者
Hong, Fei [1 ]
Guo, Xinan [1 ]
Zhang, Hao [1 ]
Wei, Bin [1 ]
Zhang, Jianhua [1 ]
Wang, Jun [1 ]
机构
[1] Shanghai Univ, Key Lab Adv Display & Syst Applicat, Minist Educ, Shanghai 200072, Peoples R China
基金
中国国家自然科学基金;
关键词
Molecular template; Highly oriented film; Organic transistor; SEMICONDUCTOR;
D O I
10.1016/j.orgel.2009.05.022
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Highly oriented copper phthalocyanine (CuPc) film consisting of many crystal domains was prepared by introducing titanyl-phthalocyanine (TiOPc) as molecular template at high substrate temperature. CuPc molecules stand up on the top of TiOPc domains exhibiting herringbone structure and high-order arrangement investigated by atomic force microscopy and X-ray diffraction. Then organic transistors were fabricated that exhibited improved device performances, a 0.12 cm(2)/V s of mobility and a 10(5) of on/off ratio. Furthermore, template thickness dependence on device performance was disclosed. These results indicated that molecular template is a very effective method to prepare high-mobility organic semiconductor film. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1097 / 1101
页数:5
相关论文
共 23 条
  • [1] Organic complementary-like inverters employing methanofullerene-based ambipolar field-effect transistors
    Anthopoulos, TD
    de Leeuw, DM
    Cantatore, E
    Setayesh, S
    Meijer, EJ
    Tanase, C
    Hummelen, JC
    Blom, PWM
    [J]. APPLIED PHYSICS LETTERS, 2004, 85 (18) : 4205 - 4207
  • [2] Organic field-effect transistors with high mobility based on copper phthalocyanine
    Bao, Z
    Lovinger, AJ
    Dodabalapur, A
    [J]. APPLIED PHYSICS LETTERS, 1996, 69 (20) : 3066 - 3068
  • [3] Highly ordered vacuum-deposited thin films of metallophthalocyanines and their applications in field-effect transistors
    Bao, ZN
    Lovinger, AJ
    Dodabalapur, A
    [J]. ADVANCED MATERIALS, 1997, 9 (01) : 42 - &
  • [4] Bayliss SM, 2000, ADV MATER, V12, P202, DOI 10.1002/(SICI)1521-4095(200002)12:3<202::AID-ADMA202>3.0.CO
  • [5] 2-L
  • [6] Titanyl phthalocyanine/C60 heterojunctions:: Band-edge offsets and photovoltaic device performance
    Brumbach, Michael
    Placencia, Diogenes
    Armstrong, Neal R.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (08) : 3142 - 3151
  • [7] Large-scale complementary integrated circuits based on organic transistors
    Crone, B
    Dodabalapur, A
    Lin, YY
    Filas, RW
    Bao, Z
    LaDuca, A
    Sarpeshkar, R
    Katz, HE
    Li, W
    [J]. NATURE, 2000, 403 (6769) : 521 - 523
  • [8] Control of threshold voltage and hysteresis in organic field-effect transistors
    Kawaguchi, Hideyuki
    Taniguchi, Masateru
    Kawai, Tomoji
    [J]. APPLIED PHYSICS LETTERS, 2009, 94 (09)
  • [9] Kelley TW, 2003, MATER RES SOC SYMP P, V771, P169
  • [10] An ultra closely π-stacked organic semiconductor for high performance field-effect transistors
    Li, Liqiang
    Tang, Qingxin
    Li, Hongxiang
    Yang, Xiaodi
    Hu, Wenping
    Song, Yabin
    Shuai, Zhigang
    Xu, Wei
    Liu, Yunqi
    Zhu, Daoben
    [J]. ADVANCED MATERIALS, 2007, 19 (18) : 2613 - +