Hierarchical nanoporous gold film electrode with extra high surface area and electrochemical activity

被引:25
作者
Jia, Falong [1 ]
Yu, Chuanfang [1 ]
Zhang, Lizhi [1 ]
机构
[1] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China
基金
美国国家科学基金会;
关键词
Alloying/dealloying; Hierarchical nanoporous structure; Gold; Multi-cyclic electrochemical scan; FABRICATION; METALS; REDUCTION; OXIDATION; EVOLUTION; METHANOL;
D O I
10.1016/j.elecom.2009.08.023
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This paper describes the fabrication and electrochemical behavior of hierarchical nanoporous gold film (HNPGF) electrode by multi-cyclic electrochemical co-alloying/dealloying of two sacrifice metals (Zn and Sn) with gold. Different from the nanoporous gold film (NPGF) formed in the electrolyte of ZnCl2 in benzyl alcohol, the HNPGF obtained possessed special hierarchical porous structure and extra high roughness factor of 1250. This study reveals that hierarchical porous gold film electrodes are promising for catalysis. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1944 / 1946
页数:3
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