2,3-Di-O-benzoyl-1-O-p-nitrophenyl-6-O-pivaloyl-4-O-(3',4',6'-tri-O-acetyl-2'-deoxy-2'-N-phthalimido-beta-D-1'-glucopyranosyl)-beta-D-glucopyranose

被引:4
作者
Abboud, KA
Toporek, SS
Horenstein, BA
机构
[1] Department of Chemistry, University of Florida, PO Box 117200, Gainesville
关键词
D O I
10.1107/S0108270197000097
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title compound, C51H50N2O20, is an intermediate in the synthesis of a substrate to be used in enzymological studies of lysozyme. It was synthesized via a trichloroacetimidate coupling of 2,3,6-tri-O-acetyl-2-deoxy-2-N-phthalimido-1-trichloroacetimidate-beta-D-glucopyranoside and p-nitrophenyl 2,3-di-O-benzoyl-6-O-pivaloyl-beta-D-glucopyranoside. Both glucose rings adopt chair conformations with one described as C-1(4) and the other as C-5(3). Atoms C1 and C4 are at distances of 0.727 (4) and -0.652(4) Angstrom, respectively, and O5' and C3' are at distances of 0.713 (4) and -0.555 (5) Angstrom, respectively, from their chair planes.
引用
收藏
页码:742 / 744
页数:3
相关论文
共 8 条
[1]  
ABBOUD KA, 1996, ACTA CRYSTALLOGR C, V53, P118
[2]   THE DEVELOPMENT OF VERSION-3 AND VERSION-4 OF THE CAMBRIDGE STRUCTURAL DATABASE SYSTEM [J].
ALLEN, FH ;
DAVIES, JE ;
GALLOY, JJ ;
JOHNSON, O ;
KENNARD, O ;
MACRAE, CF ;
MITCHELL, EM ;
MITCHELL, GF ;
SMITH, JM ;
WATSON, DG .
JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES, 1991, 31 (02) :187-204
[3]  
BUCOURT R, 1974, TOPICS STEREOCHEMIST, V8
[4]   ON ENANTIOMORPH-POLARITY ESTIMATION [J].
FLACK, HD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881
[5]   APPLICATION OF TRICHLORACETAMIDE PROCESSES TO 2-DEOXY-2-PHTHALIMIDO-D-GLUCOSE DERIVATIVES - SYNTHESIS OF OLIGOSACCHARIDES OF THE CORE REGION OF ORTHO-GLYCOPROTEINS OF MUCINE TYPE [J].
GRUNDLER, G ;
SCHMIDT, RR .
CARBOHYDRATE RESEARCH, 1985, 135 (02) :203-218
[6]   CRYSTAL-STRUCTURES OF ACETALS .14. THE CRYSTAL-STRUCTURE OF 1,2,3,4,6-PENTA-O-ACETYL-ALPHA-D-GLUCOPYRANOSE [J].
JONES, PG ;
SHELDRICK, GM ;
KIRBY, AJ ;
GLENN, R .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1982, 161 (3-4) :237-243
[7]  
SHELDRICK GM, 1995, SHELXTL VERSION 5 03
[8]  
*SIEM, 1995, SMART SAINT DAT COLL