Low-temperature coating of sol-gel anatase thin films

被引:60
作者
Yun, YJ
Chung, JS
Kim, S
Hahn, SH
Kim, EJ
机构
[1] Univ Ulsan, Dept Chem Engn, Nam Ku, Ulsan 680749, South Korea
[2] Univ Ulsan, Dept Phys, Ulsan 680749, South Korea
关键词
sol-gel; titania; thin films; low-temperature coating; photoactivity;
D O I
10.1016/j.matlet.2004.07.018
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Transparent nanocrystalline TiO2 thin films were deposited on soda lime glass (SLG) at a low temperature by a simple sol-gel dip-coating method. TiO2 sols were prepared from titanium alkoxide in acidic aqueous solutions and were subsequently refluxed at 80 degreesC for 8 h, leading to the formation of anatase crystallites. The as-deposited TiO2 films were heated at 115 degreesC for 15 min. The resulting films consisted of uniform spherical particles of about 20 nm in size and had excellent photoactivity for the degradation of ethanol. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:3703 / 3706
页数:4
相关论文
共 23 条
[1]   Rutile formation in hydrothermally crystallized nanosized titania [J].
Bacsa, RR ;
Gratzel, M .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1996, 79 (08) :2185-2188
[2]   Spectroscopic ellipsometry of TiO2 layers prepared by ion-assisted electron-beam evaporation [J].
Bhattacharyya, D ;
Sahoo, NK ;
Thakur, S ;
Das, NC .
THIN SOLID FILMS, 2000, 360 (1-2) :96-102
[3]  
Chemseddine A, 1999, EUR J INORG CHEM, P235, DOI 10.1002/(SICI)1099-0682(19990202)1999:2<235::AID-EJIC235>3.0.CO
[4]  
2-N
[5]   Electrochromic properties of TiO2 anatase thin films prepared by a dipping sol-gel method [J].
Dinh, NN ;
Oanh, NTT ;
Long, PD ;
Bernard, MC ;
Goff, AHL .
THIN SOLID FILMS, 2003, 423 (01) :70-76
[6]   Properties of the TiO2 membranes prepared by CVD of titanium tetraisopropoxide [J].
Ha, HY ;
Nam, SW ;
Lim, TH ;
Oh, IH ;
Hong, SA .
JOURNAL OF MEMBRANE SCIENCE, 1996, 111 (01) :81-92
[7]   X-ray photoelectron diffraction study of an anatase thin film:: TiO2(001) [J].
Herman, GS ;
Gao, Y ;
Tran, TT ;
Osterwalder, J .
SURFACE SCIENCE, 2000, 447 (1-3) :201-211
[8]   Formation of anatase nanocrystals in sol-gel derived TiO2-SiO2 thin films with hot water treatment [J].
Kotani, Y ;
Matsuda, A ;
Tatsumisago, M ;
Minami, T ;
Umezawa, T ;
Kogure, T .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2000, 19 (1-3) :585-588
[9]   EFFECT OF PEPTIZATION ON DENSIFICATION AND PHASE-TRANSFORMATION BEHAVIOR OF SOL GEL-DERIVED NANOSTRUCTURED TITANIA [J].
KUMAR, KNP ;
KUMAR, J ;
KEIZER, K .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1994, 77 (05) :1396-1400
[10]   Sol-gel preparation of photocatalytic TiO2 films on polymer substrates [J].
Langlet, M ;
Kim, A ;
Audier, M ;
Herrmann, JM .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2002, 25 (03) :223-234