Liquid crystalline metal phthalocyanines: Structural organization on the substrate surface

被引：67

作者：

Basova, Tamara ^{[1
,2
]}

Hassan, Aseel ^{[3
]}

Durmus, Mahmut ^{[4
]}

Gurek, Ayse Gul ^{[4
]}

Ahsen, Vefa ^{[4
]}

机构：

[1] Nikolaev Inst Inorgan Chem SB RAS, 3 Lavrentiev Ave, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Pirogova Str 2, Novosibirsk 630090, Russia

[3] Sheffield Hallam Univ, Mat & Engn Res Inst, Sheffield S1 1WB, S Yorkshire, England

[4] Gebze Inst Technol, Dept Chem, POB 141, TR-41400 Gebze, Kocaeli, Turkey

来源：

COORDINATION CHEMISTRY REVIEWS | 2016年 / 310卷

基金：

俄罗斯科学基金会;

关键词：

Metal phthalocyanines; Liquid crystals; Thin films; Film alignment; UNIFORM HOMEOTROPIC ALIGNMENT; CHARGE-TRANSPORT PROPERTIES; LANGMUIR-BLODGETT-FILMS; SUBSTITUTED PHTHALOCYANINES; MESOMORPHIC PROPERTIES; THIN-FILMS; SELF-ORGANIZATION; LEAD PHTHALOCYANINES; MAGNETIC-PROPERTIES; UNIAXIAL ALIGNMENT;

D O I：

10.1016/j.ccr.2015.11.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The use of metallo phthalocyanines (MPcs) in technological applications requires certain methodological approaches for thin film fabrication. Among these applications the implementation of MPc films is in electronic devices such as organic field-effect transistors (OFETs) and photovoltaic (PV) devices. For such applications the control of alignment and ordering of MPc molecules within the films remains a considerable challenge. This review provides an overview of films' growth of mesogeriic MPcs offering systematic analysis of the influence of different factors on the structural organization of liquid crystalline phthalocyanine films, including phthalocyanines molecular structure, regimes of heating, substrate materials, and type of interfaces. The achievements in the development of methods and approaches for the formation of liquid crystalline phthalocyanine films with controllable alignment and ordering are discussed in sufficient details. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：131 / 153

页数：23

共 154 条

[61] Synthesis and mesomorphic properties of tetra- and octa-substituted phthalocyanines [J].