Synthesis of [3+3] β-ketoenamine-tethered covalent organic frameworks (COFs) for high-performance supercapacitance and CO2 storage

被引:68
作者
El-Mandy, Ahmed F. M. [1 ,2 ]
Hung, Ying-Hui [1 ]
Mansoure, Tharwat Hassan [2 ,3 ,4 ]
Yu, Hsiao-Hua [3 ,4 ,5 ]
Hsu, Yu-Shen [6 ]
Wu, Kevin C. W. [6 ,8 ]
Kuo, Shiao-Wei [1 ,7 ]
机构
[1] Natl Sun Yat Sen Univ, Ctr Crystal Res, Dept Mat & Optoelect Sci, Kaohsiung 80424, Taiwan
[2] Assiut Univ, Fac Sci, Chem Dept, Assiut 71516, Egypt
[3] Acad Sinica, Taiwan Int Grad Program, Nanosci & Technol Program, Inst Chem, Taipei 11529, Taiwan
[4] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
[5] Natl Chiao Tung Univ, Ctr Emergent Funct Matter Sci, Hsinchu 30010, Taiwan
[6] Natl Taiwan Univ, Dept Chem Engn, 1,Sec 4,Roosevelt Rd, Taipei 10617, Taiwan
[7] Kaohsiung Med Univ, Dept Med & Appl Chem, Kaohsiung 807, Taiwan
[8] Natl Taiwan Univ NTU MST, Int Grad Program Mol Sci & Technol, 1,Sec 4,Roosevelt Rd, Taipei 10617, Taiwan
关键词
Covalent-organic frameworks (COFs); Ketoenamine; Schiff-base [3+3] polycondensations; Supercapacitors; CO2; storage; 3-DIMENSIONAL NITROGEN; ANODE MATERIALS; DIFFERENT KINDS; DOPED GRAPHENE; CARBON; CONSTRUCTION; CRYSTALLINE; EFFICIENT; POLYMER; DESIGN;
D O I
10.1016/j.jtice.2019.07.016
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
We report three new beta-ketoenamine-linked covalent organic frameworks (COFs) prepared through Schiff-base [3+3] polycondensations of 1,3,5-triformylphloroglucinol (TFP-3OHCHO) with three tris(aminophenyl)-presenting derivatives-featuring amino, carbazole, and pyridine units, respectively under solvothermal conditions. The resultant TFP-COFs possessed high BET specific surface area up to 686 m(2) g(-1) and excellent crystallinity, which showed excellent electrochemical specific capacitances (up to 291.1 F g(-1)) and CO2 uptake efficiency up to 200 mg g(-1) at 273 K. We propose the enhanced performance in supercapacitor and gas storage is owing to the conjugated enamine structures with redox-active triphenyl amino, carbazole, and pyridine moieties. In addition, we further investigate the formation mechanism of the spherical TFP-TPA COF by studying the morphological changes over time. The presence of more highly planar monomer units in the hexagonal structures of the resultant COFs led to stronger quadrupolar interaction with the included CO2 molecules. (C) 2019 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:199 / 208
页数:10
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