Nanopowders of YAl3(BO3)4 doped by Nd, Yb and Cr obtained by sol-gel method: Synthesis, structure and luminescence properties

被引：12

作者：

Szysiak, A. ^{[1
]}

Lipinska, L. ^{[1
]}

Ryba-Romanowski, W. ^{[2
]}

Solarz, P. ^{[2
]}

Diduszko, R. ^{[1
]}

Pajaczkowska, A. ^{[1
]}

机构：

[1] Inst Elect Mat Technol, PL-01919 Warsaw, Poland

[2] Polish Acad Sci, Inst Low Temp & Struct Res, PL-50950 Wroclaw, Poland

来源：

MATERIALS RESEARCH BULLETIN | 2009年 / 44卷 / 12期

关键词：

Inorganic materials; Sol-gel chemistry; X-ray diffraction; Luminescence; YTTRIUM ALUMINUM BORATE; GROWTH; CRYSTALS; LASER; GD;

D O I：

10.1016/j.materresbull.2009.08.004

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Structure, morphology and luminescence properties of nanocrystalline samples of YAl3(BO3)(4) (YAB) undoped and doped with neodymium, ytterbium and Chromium obtained by the sol-gel method are presented. The best results of synthesis are obtained for mannitol as polymerizing agent. Single phase of nanopowder is obtained for pure YAB. Dopants destroy the compound structure; two other Compounds, namely Al18B4O33 and YBO3, were revealed by X-ray investigation. Nanopowders show isometric and needles forms, the calculated size of crystallites is about 60 nm. Their optical properties are determined and results are compared to data obtained for single crystal counterparts. It is shown that the influence of rare earth ions incorporated into YBO3 Phase on luminescent spectra and excited state relaxation dynamics of the nanopowders is negligibly small when the YBO3 content is of the order of several wt%. Residual impurity phases do not affect significantly spectroscopic properties of YAB nanopowders. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：2228 / 2232

页数：5

共 14 条

[11] Er:YAB nanoparticles and vitreous thin films by the polymeric precursor method [J].