Assembly of unusual Zn-cluster compounds based on pyridinealcohol platforms

被引：5

作者：

Anselmo, Daniele ^{[1
]}

Escudero-Adan, Eduardo C. ^{[1
]}

Benet-Buchholz, Jordi ^{[1
]}

Kleij, Arjan W. ^{[1
,2
]}

机构：

[1] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

[2] ICREA, Barcelona 08010, Spain

来源：

DALTON TRANSACTIONS | 2009年 / 36期

关键词：

BINUCLEAR METAL CENTER; PHOSPHOLIPASE-C; CRYSTAL-STRUCTURE; RESOLUTION; COMPLEXES; RECOGNITION; MODELS; ION; CO2;

D O I：

10.1039/b901394f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The assembly formation of Zn cluster compounds comprising pyridinealcohol ligands is described and their solution and solid state features have been determined using NMR spectroscopy and X-ray diffraction. The di-Zn complex 5 and tetra-Zn complex 7 may serve as accessible structural models for the active site of various multinuclear Zn-containing metalloenzymes. Their phosphoester cleavage activity was tested and correlated with their dynamic structural features.

引用

页码：7368 / 7373

页数：6

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