The relative rate of hydrolysis of a series of acyclic and six-membered cyclic acetals, ketals, orthoesters, and orthocarbonates

被引：83

作者：

Deslongchamps, P ^{[1
]}

Dory, YL ^{[1
]}

Li, SG ^{[1
]}

机构：

[1] Univ Sherbrooke, Inst Pharmacol Sherbrooke, Dept Chim, Synth Organ Lab, Sherbrooke, PQ J1H 5N4, Canada

来源：

TETRAHEDRON | 2000年 / 56卷 / 22期

基金：

加拿大自然科学与工程研究理事会;

关键词：

ketals; orthoesters; orthocarbonates; stereoelectronic effects; hydrolysis;

D O I：

10.1016/S0040-4020(00)00270-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The relative rate of hydrolysis of these compounds is rationalized by considering the influence of steric, inductive and stereoelectronic effects on the hydrolysis reaction mechanism. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：3533 / 3537

页数：5

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