Electric modulation of conduction in MAPbBr3 single crystals

被引:14
|
作者
Ke, Shanming [1 ]
Luo, Shangyu [1 ]
Gong, Jinhui [1 ]
Qiu, Liwen [1 ]
Liang, Renhong [1 ]
Zhou, Yangbo [1 ]
Luo, Bingcheng [1 ,2 ]
Cheng, Baochang [1 ]
Wang, Li [1 ]
Shu, Longlong [1 ]
机构
[1] Nanchang Univ, Sch Mat Sci & Engn, Nanchang 330031, Jiangxi, Peoples R China
[2] Northwestern Polytech Univ, State Key Lab Solidificat Proc, Xian 710072, Peoples R China
基金
中国国家自然科学基金;
关键词
resistive switching (RS); rectifying behavior; hybrid organic-inorganic perovskites; p-n structure; RESISTIVE SWITCHING BEHAVIOR; HALIDE PEROVSKITES; CH3NH3PBI3; QUALITY; GROWTH;
D O I
10.1007/s40145-020-0442-1
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The resistive switching (RS) mechanism of hybrid organic-inorganic perovskites has not been clearly understood until now. A switchable diode-like RS behavior in MAPbBr(3) single crystals using Au (or Pt) symmetric electrodes is reported. Both the high resistance state (HRS) and low resistance state (LRS) are electrode-area dependent and light responsive. We propose an electric-field-driven inner p-n junction accompanied by a trap-controlled space-charge-limited conduction (SCLC) conduction mechanism to explain this switchable diode-like RS behavior in MAPbBr(3) single crystals.
引用
收藏
页码:320 / 327
页数:8
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