Accurate fluorescent polymeric thermometers containing an ionic component

被引:62
作者
Gota, Chie [1 ]
Uchiyama, Seiichi [1 ]
Ohwada, Tomohiko [1 ]
机构
[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Bunkyo Ku, Tokyo 1130033, Japan
关键词
D O I
10.1039/b615168j
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Fluorescent polymeric thermometers consisting of only N-alkylacrylamide and fluorescent components show rather low temperature resolution in their functional ranges (ca. 15-50 degrees C) because of the occurrence of intermolecular aggregation, which causes hysteresis in their fluorescence response to changes in temperature. By adding an ionic component to prevent such intermolecular aggregation, we obtained four fluorescent polymeric thermometers that offer high temperature resolution (<0.2 degrees C). Each new fluorescent polymeric thermometer covered the temperature range, 9-33 degrees C, 30-51 degrees C, 49-66 degrees C or 4-38 degrees C.
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页码:121 / 126
页数:6
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