Branched carbon-rich luminescent multinuclear platinum(II) and palladium(II) alkynyl complexes with phosphine ligands

被引：44

作者：

Tao, Chi-Hang

Yam, Vivian Wing-Wah ^{[1
]}

机构：

[1] Univ Hong Kong, Ctr Carbon Rich Mol & Nanoscale Met Based Mat Res, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS | 2009年 / 10卷 / 03期

关键词：

Luminescence; Platinum(II) complexes; Palladium(II) complexes; Two-photon induced luminescence; NONLINEAR-OPTICAL PROPERTIES; 2-PHOTON ABSORPTION; ORGANOMETALLIC DENDRIMERS; ORGANIC-MOLECULES; MLCT TRANSITION; SPECTROSCOPY; ACETYLIDES; CRYSTAL; SINGLET; POLYMER;

D O I：

10.1016/j.jphotochemrev.2009.06.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this review, the synthesis, electronic absorption and luminescent properties of a series of branched alkynylpalladium(II) and -platinum(II) phosphine complexes with different alkynyl backbones and some of their structurally related complexes in the literature will be discussed. With the growing research interest in the potential application of these complexes in the field of non-linear optics (NLO), the two-photon absorption (TPA) properties and the corresponding structure-property relationships of selected luminescent branched platinum(II) bis-alkynyl complexes will also be described. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：130 / 140

页数：11

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