Thermodynamic modeling of the C-Pu-U system

被引：2

作者：

Fischer, Evelyne ^{[1
]}

机构：

[1] Grenoble INP, F-38400 St Martin Dheres, France

来源：

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY | 2009年 / 33卷 / 03期

关键词：

C-Pu-U; Thermodynamics; Modeling; CALPHAD;

D O I：

10.1016/j.calphad.2009.01.004

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The ternary C-Pu-U system is thermodynamically assessed to pursue the development of a thermodynamic database for future nuclear fuels. The substitution model was used for the liquid phase, and a two-sublattice model for the PuC-UC monocarbide, PuC(2)-UC(2) dicarbide and Pu(2)C(3)-U(2)C(3) sesquicarbide phases. Ternary interaction parameters were adjusted on the experimental information for the phase relationships. Isoplethal and isothermal ternary sections, as well as some liquidus temperatures are calculated and compared with the experimental data. The overall agreement is discussed, and shows that experimental uncertainties still remain. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：487 / 494

页数：8

共 20 条

[1]

BROWNING P, 1976, PLUTONIUM OTHER ACTI, P257

[2] Thermodynamic modelling of the C-U and B-U binary systems [J].

Chevalier, PY ;

Fischer, E .

JOURNAL OF NUCLEAR MATERIALS, 2001, 288 (2-3) :100-129

[3]

Cheynet B., 2007, MEPHISTA THERMODYNAM

[4]

DALTON JT, 1969, 5948 UKAEA AERER

[5]

DALTON JT, 1964, CARBIDES NUCL ENERGY, P71

[6] SGTE DATA FOR PURE ELEMENTS [J].

DINSDALE, AT .

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1991, 15 (04) :317-425

[7] Thermodynamic modeling of the C-Pu system [J].

Fischer, Evelyne .

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2008, 32 (02) :371-377

[8]

HOLLECK H, 1974, THERMODYNAMICS NUCL, V2, P213

[9] Thermodynamic assessment of the Pu-U, Pu-Zr, and Pu-U-Zr systems [J].

Kurata, M .

CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 1999, 23 (3-4) :305-337

[10]

MARDON PG, 1970, AERER6514

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