Synthesis and structure of [Mo2O4(acac)2thala]•3C2H5OH with thala=3-(2-thienyl)-DL-alanine as a third bridging ligand between two molybdenum atoms

被引：10

作者：

Cindric, M

Strukan, N

Kajfez, T

Giester, G

Kamenar, B

机构：

[1] Univ Zagreb, Fac Sci, Lab Gen & Inorgan Chem, HR-10001 Zagreb, Croatia

[2] Univ Vienna, Inst Mineral & Crystallog, A-1090 Vienna, Austria

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 06期

关键词：

crystal structures; molybdenum complexes; oxo complexes; amino acid complexes;

D O I：

10.1016/S1387-7003(00)00072-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

As part of our study on oxomolybdenum(V) complexes we present here the synthesis and crystal structure of a novel dimeric oxomolybdate(V) [Mo2O4(acac)(2)thala] . 3C(2)H(5)OH (acac = acetylacetonato, thala = 3-(2-thienyl)-DL-alanine) in which two molybdenum atoms are bring bridged not only by two ore-oxygens but additionally by the amino acid carboxylate group. Two octahedrally coordinated molybdenum atoms are singly bonded to each other at a distance of 2.5631(5) Angstrom. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：281 / 284

页数：4

共 21 条

[1] TRIPLY BRIDGED BINUCLEAR THIOLATE COMPLEXES OF OXOMOLYBDENUM(V) - SYNTHESIS OF [MO2O2(SR)6Z]-(Z=OR',SR',NR'2) AND CRYSTAL-STRUCTURES OF (ET4N)[MO2O2(SCH2CH2O)2CL3] (ET4N)[MO2O2(SCH2CH2O)3CL] AND (PR3NH)[MO2O2(SCH2CH2O)3(SCH2CH2OH)] [J].