Silicon-containing ferritic/martensitic steel after exposure to oxygen-containing flowing lead-bismuth eutectic at 450 and 550 °C

被引:52
作者
Schroer, Carsten [1 ]
Koch, Verena [1 ,2 ]
Wedemeyer, Olaf [1 ]
Skrypnik, Aleksandr [1 ]
Konys, Juergen [1 ]
机构
[1] KIT, Inst Angew Mat Angew Werkstoffphys IAM AWP, Hermann von Helmholtz Pl 1, D-76344 Eggenstein Leopoldshafen, Germany
[2] Robert Bosch GmbH, Stuttgart, Germany
关键词
Fast reactor; Accelerator driven system; Liquid metal corrosion; Oxidation; CORROSION-RESISTANCE; AUSTENITIC STEEL; TEMPERATURE; OXIDATION; BEHAVIOR; T91;
D O I
10.1016/j.jnucmat.2015.11.058
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A ferritic/martensitic (f/m) steel with 9 and 3 mass% of chromium (Cr) and silicon (Si), respectively, was tested on performance in flowing lead-bismuth eutectic (LBE) at 450 and 550 degrees C, each at concentrations of solved oxygen of both 10(-7) and 10(-6) mass%. The 9Cr-3Si steel generally exhibits the same basic corrosion modes as other f/m materials with 9 mass% Cr and typically lower Si content, namely Steel T91. The Si-rich steel shows an overall improved performance in comparison to T91 at 450 degrees C and 10(-7) mass% solved oxygen, but especially at 450 degrees C and 10(-6) mass% solved oxygen. The advantage of higher Si-content in 9Cr steel is less clear at 550 degrees C. Especially high oxygen content in flowing LBE at 550 degrees C, between >10(-6) mass% and oxygen saturation, seems detrimental for the high-Si material in respect of the initiation and progress of a solution-based corrosion.
引用
收藏
页码:162 / 176
页数:15
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