Effect of P on glass forming ability, magnetic properties and oxidation behavior of FeSiBP amorphous alloys

被引:54
作者
Wang, Chengjuan [1 ,2 ]
He, Aina [2 ,3 ]
Wang, Anding [2 ,3 ]
Pang, Jing [1 ]
Liang, Xiaofeng [1 ,2 ]
Li, Qingfeng [1 ]
Chang, Chuntao [2 ,3 ]
Qiu, Keqiang [1 ]
Wang, Xinmin [2 ,3 ]
机构
[1] Shenyang Univ Technol, Coll Mat Sci & Engn, 111 Shenliao West Rd, Shenyang 110870, Liaoning, Peoples R China
[2] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Key Lab Magnet Mat & Devices, Ningbo 315201, Zhejiang, Peoples R China
[3] Chinese Acad Sci, Ningbo Inst Mat Technol & Engn, Zhejiang Prov Key Lab Magnet Mat & Applicat Techn, Ningbo 315201, Peoples R China
基金
中国国家自然科学基金;
关键词
Amorphous metals; Glass-forming ability; Magnetic properties; Oxidation; BULK METALLIC GLASSES; STABILITY;
D O I
10.1016/j.intermet.2016.12.024
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effect of P on the glass forming ability, soft magnetic properties and oxidation behavior of Fe78B13Si9-xPx (x = 0-7) amorphous alloys were investigated. It is found that the proper introduction of P, can effectively improve the glass forming ability and stability of supercooled liquid region. Fe78Si4B13P5 BMG, which exhibits high saturation flux density of 1.56 T, was readily made into rod sample with a diameter of 1.5 mm under air casting atmosphere. P bearing alloys also exhibit excellent soft magnetic properties containing low coercivity of 1.7-2.7 A/m, and high effective permeability of 8200-12,200. Slight oxidation can further improve the coercivity to a lower value of 1.1 A/m and the higher effective permeability to 11,900 for the alloys with P content no more than 3 at. %. Excessive addition of P may deteriorate the glass forming ability, soft magnetic properties and oxidation behavior. Magnetic domain revealing the magnetization process of the amorphous ribbons were characterized to explain the effect of P on magnetic properties and oxidation behavior. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:142 / 147
页数:6
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