Pauli-like magnetic susceptibility in emeraldine base polyaniline

被引：8
|
作者：
Kahol, PK [1 ]
机构：
[1] Wichita State Univ, Dept Phys, Wichita, KS 67260 USA
来源：
SOLID STATE COMMUNICATIONS | 2002年 / 124卷 / 03期
关键词：
polymers; electronic transport;
D O I：
10.1016/S0038-1098(02)00480-5
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
Magnetic susceptibility measurements on emeraldine base (EB) polyaniline are found to exhibit a Pauli-like behavior up to a temperature of 475 K. A simple albeit physically realistic model involving spin-pairs is shown to lead to such a dependence on temperature. The analysis of the data indicates that polarons in EB are created in pairs and that the intra-pair interactions encompass a broad distribution of antiferromagnetic exchange couplings. The results on EB are further shown to have essential implications for a correct interpretation of the magnetic susceptibility data in doped conducting polymers. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：93 / 96
页数：4
相关论文
共 50 条
  • [21] TRANSFORMATION OF THE DIRAC HAMILTONIAN INTO VARIATIONAL PAULI-LIKE HAMILTONIANS - APPLICATION TO HYDROGEN-LIKE ATOMS
    DURAND, P
    COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II, 1986, 303 (02): : 119 - &
  • [22] Preparation of Se-doped polyaniline emeraldine base films
    Bormashenko, E
    Pogreb, R
    Sutovski, S
    Shulzinger, A
    Sheshnev, A
    Gladkikh, A
    SYNTHETIC METALS, 2003, 139 (02) : 321 - 325
  • [23] Infrared optics applications of thin polyaniline emeraldine base films
    Bormashenko, E
    Pogreb, R
    Sutovski, S
    Shulzinger, A
    Sheshnev, A
    Izakson, G
    Katzir, A
    SYNTHETIC METALS, 2004, 140 (01) : 49 - 52
  • [24] KINETIC-STUDY ON CHEMICAL OXIDATION OF LEUCOEMERALDINE BASE POLYANILINE TO EMERALDINE BASE
    MOON, DK
    EZUKA, M
    MARUYAMA, T
    OSAKADA, K
    YAMAMOTO, T
    MACROMOLECULES, 1993, 26 (02) : 364 - 369
  • [25] Preparation of Se-doped polyaniline emeraldine base films
    Bormashenko, E
    Pogreb, R
    Sutovski, S
    Shulzinger, A
    Sheshnev, A
    Gladkikh, A
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U705 - U705
  • [26] Infrared optics applications of thin polyaniline emeraldine base films
    Bormashenko, E
    Pogreb, R
    Sutovski, S
    Shulzinger, A
    Sheshnev, A
    Izakson, G
    Katzir, A
    ORGANIC PHOTONIC MATERIALS AND DEVICES V, 2003, 4991 : 445 - 451
  • [27] POLYANILINE - NONOXIDATIVE DOPING OF THE EMERALDINE BASE FORM TO THE METALLIC REGIME
    HUANG, WS
    MACDIARMID, AG
    EPSTEIN, AJ
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (23) : 1784 - 1786
  • [28] Optical spectroscopic studies of pernigraniline and emeraldine base forms of polyaniline
    Chandrakanthi, RLN
    Careem, MA
    SYNTHETIC METALS, 2003, 135 (1-3) : 337 - 338
  • [29] REGULAR TWO-COMPONENT PAULI-LIKE EFFECTIVE HAMILTONIANS IN DIRAC THEORY.
    Chang, Ch.
    Pelissier, M.
    Durand, Ph.
    Physica Scripta, 1986, 34 (05) : 394 - 404
  • [30] Methanol as a Suitable Solvent for Polyaniline Emeraldine Base (PANI-EB)
    Othman, Siti Amira
    Radiman, Shahidan
    Siong, Khoo Kok
    PROGRESS OF PHYSICS RESEARCH IN MALAYSIA, PERFIK2009, 2010, 1250 : 357 - 360
12345