A highly active Fe(I) catalyst for radical polymerisation and taming the polymerisation with iodine

被引：36

作者：

Kamigaito, M ^{[1
]}

Onishi, I ^{[1
]}

Kimura, S ^{[1
]}

Kotani, Y ^{[1
]}

Sawamoto, M ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Polymer Chem, Kyoto 6068501, Japan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 22期

关键词：

D O I：

10.1039/b206651c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A fast and controlled radical polymerisation of acrylates and acrylamides can be achieved with a combination of a highly active metal catalyst, Fe2Cp2(CO)(4), and a mild radical scavenger, iodine, in the presence of an iodide initiator.

引用

页码：2694 / 2695

页数：2

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