Enantioselective palladium-catalysed conjugate addition of arylsiloxanes

被引:47
作者
Gini, Francesca [1 ]
Hessen, Bart [1 ]
Feringa, Ben L. [1 ]
Minnaard, Adriaan J. [1 ]
机构
[1] Univ Groningen, Stratingh Inst, NL-9747 AG Groningen, Netherlands
关键词
D O I
10.1039/b616969d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The complex formed from Pd(CH3CN)(4)(BF4)(2) and (R,R)-MeDUPHOS is a highly enantioselective catalyst for the asymmetric conjugate addition of aryltriethylsiloxanes to a variety of unsaturated ketones, lactones and lactams.
引用
收藏
页码:710 / 712
页数:3
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