Anode property of carbon coated LiFePO4 nanocrystals

被引:9
作者
Ni, Jiangfeng [1 ]
Jiang, Jiaxing [2 ]
Savilov, S. V. [3 ]
Aldoshin, S. M. [4 ]
机构
[1] Soochow Univ, Coll Phys Optoelect & Energy, Suzhou 215006, Peoples R China
[2] Wuxi Jiefu Electroacoust Co Ltd, Wuxi 214192, Peoples R China
[3] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
[4] Moscow MV Lomonosov State Univ, Dept Phys Chem Engn, Moscow 119991, Russia
基金
中国国家自然科学基金;
关键词
Rechargeable lithium battery; lithium iron phosphate; nanocrystal; electrochemical performance; ELECTROCHEMICAL PERFORMANCE; FACILE SYNTHESIS; LITHIUM; BEHAVIOR;
D O I
10.1142/S1793604716500041
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Nanostructured LiFePO4 is appealing cathode material for rechargeable lithium batteries. Herein, however, we report the intriguing anode properties of carbon coated LiFePO4 nanocrystals. In the potential range of 0-3.0 V, the LiFePO4 nanocrystal electrodes afford high reversible capacity of 373 mAh g(-1) at a current rate of 0.05 Ag-1 and retains 239 mAh g(-1) at a much higher rate of 1.25 A g(-1). In addition, it is capable of sustaining 1000 cycles at 1.25 A g(-1) without any capacity fading. Such superior properties indicate that nanostructured LiFePO4 could also be promising anode for rechargeable battery applications.
引用
收藏
页数:4
相关论文
共 25 条
  • [21] Controlled synthesis of MnO2/CNT nanocomposites for supercapacitor applications
    Tan, D. Z. W.
    Cheng, H.
    Nguyen, S. T.
    Duong, H. M.
    [J]. MATERIALS TECHNOLOGY, 2014, 29 (A2) : A107 - A113
  • [22] Superior performance of nanoscaled Fe3O4 as anode material promoted by mosaicking into porous carbon framework
    Wan, Wang
    Wang, Chao
    Zhang, Weidong
    Chen, Jitao
    Zhou, Henghui
    Zhang, Xinxiang
    [J]. FUNCTIONAL MATERIALS LETTERS, 2014, 7 (02)
  • [23] Ultimate Limits to Intercalation Reactions for Lithium Batteries
    Whittingham, M. Stanley
    [J]. CHEMICAL REVIEWS, 2014, 114 (23) : 11414 - 11443
  • [24] Facile Synthesis of Hematite Quantum-Dot/Functionalized Graphene-Sheet Composites as Advanced Anode Materials for Asymmetric Supercapacitors
    Xia, Hui
    Hong, Caiyun
    Li, Bo
    Zhao, Bin
    Lin, Zixia
    Zheng, Mingbo
    Savilov, Serguei V.
    Aldoshin, Serguei M.
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2015, 25 (04) : 627 - 635
  • [25] High Performance LiMn1-xFexPO4 (0 ≤ x ≤ 1) Synthesized via a Facile Polymer-Assisted Mechanical Activation
    Xiao, P. F.
    Ding, B.
    Lai, M. O.
    Lu, L.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2013, 160 (06) : A918 - A926