Sunlight Oxidation of Alkyl Aryl Tellurides to the Corresponding Carbonyl Compounds: A New Carbonyl Precursor

被引：16
|
作者：
Ouchi, Akihiko [1 ,2 ]
Hyugano, Takeshi [2 ]
Liu, Chuanxiang [1 ]
机构：
[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan
[2] Univ Tsukuba, Grad Sch Pure & Appl Sci, Tsukuba, Ibaraki 3058571, Japan
来源：
ORGANIC LETTERS | 2009年 / 11卷 / 21期
关键词：
GROUP-TRANSFER CYCLIZATION; ORGANOTELLURIUM COMPOUNDS; RADICAL CYCLIZATION; GREEN PHOTOCHEMISTRY; SUBSTITUTED QUINONES; DIETHYL SELENIUM; MOLECULAR-OXYGEN; FINE CHEMICALS; SOLAR LIGHT; PHOTOLYSIS;
D O I：
10.1021/ol901943f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Alkyl aryl tellurides were efficiently transformed to the corresponding carbonyl compounds by photo-oxidation with sunlight without affecting various functional groups in the alkyl moiety. The tellurides can be used as a new carbonyl precursor, and the photolysis can be conducted without special equipment for light sources.
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页码：4870 / 4873
页数：4
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