Copper(I) complexes with N-thiophosphorylated thioureas and phosphines with versatile structures and luminescence

被引：16

作者：

Babashkina, Maria G. ^{[1
]}

Safin, Damir A. ^{[1
]}

Bolte, Michael ^{[2
]}

Klein, Axel ^{[1
]}

机构：

[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany

[2] Goethe Univ Frankfurt, Inst Anorgan Chem, Frankfurt, Germany

来源：

CRYSTENGCOMM | 2010年 / 12卷 / 01期

关键词：

RAY CRYSTAL-STRUCTURE; PSEUDO-HALOGEN; CU-I; AG-I; ADDUCTS; PH2E(CH2)(X)EPH2; DPEX; HL; TRIPHENYLPHOSPHINE; BROMIDE;

D O I：

10.1039/b914163d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of the potassium salts of RC(S)NHP(S)(OiPr)(2) (R = MeNH, HLI; iPrNH, HLII; tBuNH, HLIII; Me2N, HLIV; PhNH, HLV; 2,6-Me2C6H3NH, HLVI; 2,4,6-Me3C6H2NH, HLVII) with [Cu(PPh3)(3)I] or a mixture of CuI and Ph2P(CH2)(n)PPh2 (n = 1, 2, 3) in aqueous EtOH/CH2Cl2 leads to mononuclear 1-6, 8-10, 12-27 or binuclear 7, 11 complexes. The structures of these compounds were investigated by H-1, P-31{H-1} NMR spectroscopy and elemental anayses. The crystal structures of 1, 2, 4, 5, 11, 18, 20 and 21 were determined by single crystal X-ray diffraction. The luminescence properties of mononuclear complexes 1, 21, 22 and 27, and binuclear complexes 7 and 11 center dot C3H6O are reported.

引用

页码：134 / 143

页数：10

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