Removal of Rb(62P) by H2, CH4, and C2H6

被引:11
作者
Azyazov, V. N. [1 ,2 ]
Bresler, S. M. [3 ]
Torbin, A. P. [1 ,2 ]
Mebel, A. M. [1 ,4 ]
Heaven, M. C. [1 ,3 ]
机构
[1] Samara State Aerosp Univ, Samara 443086, Russia
[2] Lebedev Phys Inst RAS, Samara 443011, Russia
[3] Emory Univ, Atlanta, GA 30322 USA
[4] Florida Int Univ, Miami, FL 33199 USA
关键词
RUBIDIUM; COLLISIONS; N2;
D O I
10.1364/OL.41.000669
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The saturated hydrocarbons methane and ethane are often used as collisional energy transfer agents in diode-pumped alkali vapor lasers (DPALs). Problems are encountered because the hydrocarbons eventually react with the optically pumped alkali atoms, resulting in the contamination of the gas lasing medium and damage of the gas cell windows. The reactions require excitation of the more highly excited states of the alkali atoms, which can be generated in DPAL systems by energy pooling processes. Knowledge of the production and loss rates for the higher excited states is needed for a quantitative understanding of the photochemistry. In the present study, we have used experimental and theoretical techniques to characterize the removal of Rb (6(2)P) by hydrogen, methane, and ethane. (C) 2016 Optical Society of America
引用
收藏
页码:669 / 672
页数:4
相关论文
共 17 条
  • [1] ENERGY POOLING PROCESS IN RUBIDIUM VAPOR
    BARBIER, L
    CHERET, M
    [J]. JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 1983, 16 (17) : 3213 - 3228
  • [2] End-pumped continuous-wave alkali vapor lasers: experiment, model, and power scaling
    Beach, RJ
    Krupke, WE
    Kanz, VK
    Payne, SA
    Dubinskii, MA
    Merkle, LD
    [J]. JOURNAL OF THE OPTICAL SOCIETY OF AMERICA B-OPTICAL PHYSICS, 2004, 21 (12) : 2151 - 2163
  • [3] Spin-orbit relaxation and quenching of cesium 7 2P in mixtures of helium, methane, and ethane
    Brown, Kirk C.
    Perram, Glen P.
    [J]. PHYSICAL REVIEW A, 2012, 85 (02):
  • [4] Review on diode-pumped alkali vapor laser
    Gao, F.
    Chen, F.
    Xie, J. J.
    Li, D. J.
    Zhang, L. M.
    Yang, G. L.
    Guo, J.
    Guo, L. H.
    [J]. OPTIK, 2013, 124 (20): : 4353 - 4358
  • [6] Photoionization in alkali lasers
    Knize, R. J.
    Zhdanov, B. V.
    Shaffer, M. K.
    [J]. OPTICS EXPRESS, 2011, 19 (08): : 7894 - 7902
  • [7] Observation of collision induced processes in rubidium-ethane vapour
    Konefal, Z
    [J]. OPTICS COMMUNICATIONS, 1999, 164 (1-3) : 95 - 105
  • [8] Alkali-hydrogen reactions
    Lin, KC
    Vetter, R
    [J]. INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY, 2002, 21 (03) : 357 - 383
  • [9] Resonant energy transfer between highly vibrationally excited RbH(RbD) and H2(D2)
    Liu, Jing
    Shen, Xiaoyan
    Shen, Yifan
    Dai, Kang
    [J]. CHEMICAL PHYSICS, 2013, 425 : 62 - 72
  • [10] Characterization of violet emission from Rb optical pumping cells used in laser-polarized xenon NMR experiments
    Saha, Indrajit
    Nikolaou, Panayiotis
    Whiting, Nicholas
    Goodson, Boyd M.
    [J]. CHEMICAL PHYSICS LETTERS, 2006, 428 (4-6) : 268 - 276